Home
Class 12
CHEMISTRY
The decomposition of A into product has...

The decomposition of `A` into product has value of `k` as `4.5xx10^(3)s^(-1)` at `10^(@)C` and energy of activation of `60kJmol^(-1)`. At what temperature would `k` be `1.5xx10^(4)s^(-1)?`

A

273.15 k

B

`24.01^@C`

C

280.39 K

D

`45.29^@C`

Text Solution

Verified by Experts

The correct Answer is:
B

According to Arrhenius equation,
`"log"(k_(2))/(k_(1))=E_(a)/(2.303R)xx(T_(2)-T_(1))/(T_(1)T_(2))` `"log"(1.5xx10^(4))/(4.5xx10^(3))=(60000J"mol"^(-1))/(2.303xx(8.314J"mol"^(-1)))((T_(2)-283)/(283T_(2)))`
`log3.333=3.1333.62((T_(2)-283)/(283T_(2)))`
`T_(2)=297.01k=(297.01-273.0)^@C=24.01^@C`
Temperature =`24.01^@C`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|20 Videos
  • CHEMICAL KINETICS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise Exercise 1|63 Videos
  • BIOMOLECULES

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|24 Videos
  • CHEMICAL THERMODYNAMICS AND ENERGETIC

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|40 Videos

Similar Questions

Explore conceptually related problems

(a) The decomposition of A into products has a value of K as 4.5 xx 10^(3)s^(-1) " at "10^(@)C and energy of activation 60kJ "mol"^(-1) . At what temperature would K be 1.5 xx 10^(4) s^(-1) ? (b) (i) If half life period of a first order reaction is x and 3//4^(th) life period of the same reaction is y, how are x and y related to each other ? (ii) In some cases it is found that a large number of colliding molecules have energy more than threshold energy, yet the reaction is slow. Why?

A reaction has a rate constant k=8.54 xx 10^(-4)M s^(-1) at 45^(@) C and an activation energy, E_(a)=90.8KJ . What is the value of K at 25^(@) C?

The rate constant for the decomposition of hydrocarbons is 2.418xx10^(-5)s^(-1) at 546K . If the energy of activation is 179.9kJ mol^(-1) , what will be the value of pre - exponential factor?

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-CHEMICAL KINETICS -Exercise 2
  1. The rate of a reaction quadruples when the temperature changes from 29...

    Text Solution

    |

  2. The rate law for the reaction RCl + NaOH(aq) rarr ROH + NaCl is give...

    Text Solution

    |

  3. The decomposition of A into product has value of k as 4.5xx10^(3)s^(-...

    Text Solution

    |

  4. The rate constant (K') of one reaction is double of the rate constant ...

    Text Solution

    |

  5. The rate constant of the chemical reaction doubled for an increase of ...

    Text Solution

    |

  6. Powdered magnesium element catches fire more repidly than magnesium wi...

    Text Solution

    |

  7. Compounds A and B react according to the following chemical equation, ...

    Text Solution

    |

  8. For the reaction 2H(2)+O(2)rarr 2H(2)O, the rate law expression is , ...

    Text Solution

    |

  9. consider the following reaction, N(2)(g)+3H(2)(g)hArr2NH(3)(g) The...

    Text Solution

    |

  10. For a reaction Rto P, the concentration of a reactant changes from 0.0...

    Text Solution

    |

  11. Consider the following reaction, 2P(2)O(5)rarr4PO(2)(g)+O(2)(g) If...

    Text Solution

    |

  12. For the reaction, A+Brarr"product" If concentration of A is doubled,...

    Text Solution

    |

  13. The rate constant for the first order decomposition of ethylene oxide ...

    Text Solution

    |

  14. On the basis of the curve shown above, identify the correct statement(...

    Text Solution

    |

  15. Consider the following reaction, N(2)(g)+3H(2)(g)hArr 2NH(3)(g)+22kc...

    Text Solution

    |

  16. Consider the following reaction, 2A + B + C rarr Products How wi...

    Text Solution

    |

  17. Which of the following expression is correct for the rate of reac...

    Text Solution

    |

  18. The reaction Ararr B follows first order kinetics. The time taken for ...

    Text Solution

    |

  19. The rate of formation of SO(3) in the following reaction is 100 g " mi...

    Text Solution

    |

  20. Consider the following reaction, 2N(2)O(5)rarr4NO(2)+O(2),(d[NO(2)]...

    Text Solution

    |