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The rate of a reaction doubles when its ...

The rate of a reaction doubles when its temperature changes form `300 K` to `310 K`. Activation energy of such a reaction will be:
`(R = 8.314 JK^(-1) mol^(-1) and log 2 = 0.301)`

A

`53.6kJ" mol"^(-1)`

B

`48.6kJ" mol"^(-1)`

C

`58.5kJ" mol"^(-1)`

D

`60.5kJ " mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

From Arrhenius equation,
`"log"(k_(2))/(k_(1))=-E_(a)/(2.303R)((1)/(T_(2))-(1)/(T_(1)))`
Given, `k_(2)/k_(1)=2,T_(2)=310k,T_(1)=300k`
On substituting the values,
`"log"2=(-E_(a))/(2.303xx8.314)((1)/(310)-(1)/(300))` `orE_(a)=(log2xx2.303xx8.314xx310xx300)/(10)`
`E_(a)=53598.6J//"mol"=53.6kJ//"mol"`
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