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The initial rates of reaction 3 A+ 2B +C...

The initial rates of reaction `3 A+ 2B +C rarr` products at different initial concentration are given below
`{:("Initial rate, MS"^(-1),|A_(0)|M,|B_(0)|M,|C_(0)|M),(5.0xx10^(-3),0.010,0.005,0.010),(5.0xx10^(-3),0.010,0.005,0.015),(1.0xx10^(-2),0.010,0.010,0.010),(1.25xx10^(-3),0.005,0.005,0.010):}`
The order of reaction with respect to the reacts A, B and C are respectively.

A

3.2.0

B

3,2,1

C

2,2,0

D

2,1,0

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The correct Answer is:
D

1st and 2nd set of data-No change in rate with the change in concentration of C. Thus, the order with respect to reactant C is zero.
1st and 3rd set of data-On doubling the concentration of B, rate becomes double
Thus, the order with respect to reactant 'B' is 1.
1st and 4th set of data-On doubling the concentration of A rate becomes four times. Thus, the order with respect to reactant is A is 2.
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The initial rates of reaction 3 A+ 2B +C rarr products at different initial concentration are given below {:("Initial rate, MS"^(-1),|A_(0)|M,|B_(0)|M,|C_(0)|M),(5.0xx10^(-3),0.010,0.005,0.010),(5.0xx10^(-3),0.010,0.005,0.015),(10xx10^(-2),0.010,0.010,0.010),(1.25xx10^(-2),0.005,0.005,0.010):} The order of reaction with respect to the reacts A, B and C are respectively.

Rate of a reaction A + B rarr Product, is given as a function of different initial concentration of A and B . |{:([A] (mol L^(-1)),(B) (mol L^(-1)),"Initial rate" (mol L^(-1) min^(-1)),),(0.01,0.01,0.005,),(0.02,0.01,0.010,),(0.01,0.02,0.005,):}| Determine the order of the reaction with respect to A and with respect to B . What is the half life of A in the reaction ?

0.02xx0.05=0.1(b)0.010.001(d)0.0001

For the reaction : 2A +B rarr C +D , measurement of the rate of the reaction at varying concentrations are given below {:("Trial No.","[A]","[B]","rate"("m mole L"^(-1)"s"^(-1))),(1,0.010,0.010,2.5),(2,0.010,0.020,5.0),(3,0.030,0.020,45.0):} The rate law is therefore

For the reaction : 2A + B rarr C + D , measurement of the rate of the reaction at varying concentrations are given below: {:("Trial No.",[A],[B],"Rate in mol L"^(-1)s^(-1)),(1,0.010,0.010,2.5),(2,0.010,0.020,5.0),(3,0.030,0.020,45.0):} The overall order of the reaction is :

For a reaction between A and B, the initial rate of reaction is measured for various initial concentration of A and B. The data provided are {:("[A]","[B]","Initial reaction rate"),("(a) 0.02 M","0.30 M",5xx10^(-5)),("(b) 0.20 M","0.10 M",5xx10^(-5)),("(c) 0.40 M","0.05 M",1xx10^(-4)):} The overall order of the reaction is

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-CHEMICAL KINETICS -Exercise 2
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