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For which of the following pairs, magnet...

For which of the following pairs, magnetic moment is same ?

A

`MnCl_(2),CuSo_(4)`

B

`CuCl_(2),TiCl_(3)`

C

`TiO_(2),CuSO(4)`

D

`TiCl_(3) NiCl_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B

Species having the same number of unpaired electronic, have same magnetic moment.
`CuCl_(2)impliesCu^(2+)=[Ar]3d^(9),4s^(0)` (one unpaired electrons)
`TiClimpliesTi^(3+)=[Ar]3d^(1),4s` (one unpaired electron) ,
`:.CuCl^(92) and TiCl_(3)` have same magnetic moment.
`mu=sqrt(n(n+2))=sqrt24BM`
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