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Number of electrons in 3d-orbital of V^(...

Number of electrons in 3d-orbital of `V^(2+),Cr^(2+)`,`Mn^(2+)` and `Fe^(2+)` are 3,4,5, and 6 respectively. Which of te following ions will have lgargest value of magnetic moment`(mu)`?

A

`V^(2)`

B

`Cr^(2+)`

C

`Mn^(2+)`

D

`Fe^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
C

Magnetic moment `(mu)=sqrt(n(n+2))BM` where, 'n' is the number of unpaired electrons.
`._(23)V^(2+)=[Ar]3d^(3)" "(n=3)`
`._(24)Cr^(2+)=[Ar]3d^(4) " "(n=4)`
`._(25)Mn^(2+)=[Ar]3d^(5) " "(n=5)`
`._(26)Fe^(2+)=[Ar]3d^(6) " "(n=4)`
Hence, magnetic moment will be maximum for `Mn^(2+)` (equal to 5.92BM)
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-D - AND F-BLOCK ELEMENTS-Exercise 2 (Miscellaneous Problems)
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  9. Consider the followinh reaction of permaganate ions. (I)10I^(-)+2Mn...

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  15. Select the correct order of oxidising power in acidic medium.

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