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KMnO(4) can be prepared from K(2)MnO(4) ...

`KMnO_(4)` can be prepared from `K_(2)MnO_(4)` as per reaction
`3MnO_(4)^(2-)+2H_(2)OhArr2MnO_(4)^(-)+MnO_(2)+4OH^(-)`

A

HCl

B

KOH

C

`CO_(2)` is formed as the product

D

`sO_(2)`

Text Solution

Verified by Experts

The correct Answer is:
D

Since,`OH^(-)` are generated from weak acid`(H_(2)O)`. A weak acid (like `CO_(2)`) should be used to remove it because strong acid (HCl) reverse the reaction . KOH increases the concentration of `OH^(-)`,thus again sgifts the reaction in backward side . `Co_(2)` combines with `OH^(-)` to give carbonate which is easily removed. `SO_(2)`react with water to give strong acid , so it cannot be used.
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KMnO_(4) can be prepared from K_(2)MnO_(4) as per the reaction 3MnO_(4)^(2-) + 2H_(2)O hArr 2MnO_(4)^(2-) + MnO_2 + 4OH^- The reaction can go to completion by removing OH^(-) ions by adding.

K_(2)MnO_(4) can be converted to KMnO_(4) by