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Ce^(4+) is stable .This is because of...

`Ce^(4+)` is stable .This is because of

A

half-filled d-orbital

B

all paired electrons in d-orbital

C

empty orbital

D

fully filled d-orbital

Text Solution

Verified by Experts

The correct Answer is:
C

The electronic configuration of Ce is
`Ce_(58)=[Xe]4f^(1)5d^(1)6s^(2)` (predicted) or
`=[Xe]4f^(2)5d^(0)6s^(2)` (observed)
`Ce^(4+)=[Xe]4f^(0)5d^(0)6s^(0)`
Since, in `+4` oxidation state, all 4f,5d and 6s orbitals are empty and Ce gains the stable configuration of nearest inert gas . Hence, `Ce^(4+)` is most stable .
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