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Most basic hydroxide among the following...

Most basic hydroxide among the following is

A

`Lu(OH)_(3)`

B

`Eu(OH)_(3)`

C

`Yb(OH)_(3)`

D

`Ce(OH)_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D

Due to lanthanide contraction,the size of `M^(3+)` ion (ie,`Lu^(3+),Eu^(3+),Yb^(3+) and Ce^(3+)`) decreases and thus, the basic strenth of their hydroxides decreases.
The order of size of given `M^(3+)` ions is
`Ce^(3+)gtEu^(3+)gtYb^(3+)gtLu^(3+)`
`therefore` The order of basic strength of hydroxides is
`Ce(OH)_(3)gtEu(OH)_(3)gtYb(OH)_(3)gtLU(OH)_(3)`
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