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The complexes [Co(NH(3))(6)][Cr(CN)(6)] ...

The complexes `[Co(NH_(3))_(6)][Cr(CN)_(6)]` and `[Cr(NH_(3))_(6)][Co(CN)_(6)]` are the examples of which type of isomerism ?

A

linkage isomerism

B

coordination isomerism

C

ionisation isomerism

D

geometrical isomerism

Text Solution

Verified by Experts

The correct Answer is:
B
When ligands are exchanged between metal atoms, coordination isomerism results .hence
`[Co(NH_(3))_(6)][Cr(CN)_(6) ] and [Cr(NH_(3))_(6)][(Co(CN)_(6)]` represents coordination isomerism.
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-COORDINATION COMPOUNDS-Exercise 1
  1. The IUPAC name of [Co (NH(3))(5)ONO]^(2+) ion is

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  2. The possible number of the stereo isomers in [Cr(en)(2)Cl(2)]^(o+) is ...

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  3. The complexes [Co(NH(3))(6)][Cr(CN)(6)] and [Cr(NH(3))(6)][Co(CN)(6)] ...

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  4. Which can exist both as diastereoisomer and enantiomer ?

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  5. Due to the presence of ambidenate ligands coordination compounds show ...

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  6. EAN of Fe in [Fe(C(2)O(4))(3)]^(3-) is .

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  7. The correct IUPAC name of K(2)[Zn(OH)(4)] is

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  8. Match the Column and choose the correct option from the codes g...

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  9. The correct statement on the isomerism associated with the follow...

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  10. The compounds [PtCl(2)(CH(3))(4)]Br(2) and [PtBr(2)(NH(3))(4)]Cl(2) co...

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  11. Which of the following has an optical isomer? (en=ethylenediamine) ?

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  12. Which one amongst the following , exhibit geometrical isomerism ?

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  13. The correct name of the compound [Cu(NH(3))(4)](NO(3))(2), according t...

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  14. Which of the following ion does not follow EAN rule ?

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  15. A complex of the type [M(A A)(2)X(2)] is known to the optically active...

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  16. Optical isomerism is shown by octahedral complexes

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  17. The IUPAC name of [Ni (P Ph(3))(2) Cl(2) ]^(2+) is

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  18. Which one of the following has largest number of isomers?

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  19. IUPAC name of K(3)[Fe(CN)(6)] is

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  20. The number of water molecule(s) directly bonded to the metal centre in...

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