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Due to the presence of ambidenate ligand...

Due to the presence of ambidenate ligands coordination compounds show isomerism. Palladium complexes of the type `[Pd(C_(6)H_(5))_(2)(SCN)_(2)]` & `[Pd(C_(6)H_(5))_(2)(NCS)_(2)]` are

A

linkage isomerism

B

coordination isomerism

C

ionisation isomerism

D

geometrical isomerism

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The correct Answer is:
A
Complex having ambidentate ligands like SCN exhibit linkage isomerism
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Due to the presence of ambidenate ligands coordination compounds show isomerism. Palladium complexes of the type [Pd(C_(6)H_(5))_(2)(SCN)_(2)] & [Pd(C_(6H_(5))_(2)(NCS)_(2)] are

Read the passage given below and answer the following questions : The existence of coordination compounds with the same formula but different arragements of the ligands was crucial in the development of coordination chemistry. Two or more compounds with the same formula but different arrangements of the atoms are called isomers. Isomers are compounds with the same molecular formula but different structural formulas and do not necessarily share similar properties. There are many different classes of isomers, like stereoisomers, enantiomers, and geometrical isomers. There are two main forms of isomerism: structural isomerism and stereoisomerism. The different chemical formulas in structural isomers are caused either by a difference in what ligands are bonded to the central atoms or how the individual ligands are bonded to the central atoms. The following questions are multiple choice questions. Choose the most appropriate answer: Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type [Pd(C_(6)H_(5))_(2)(SCN)_(2)] and [Pd(C_(6)H_(5))_(2)(NCS)_(2)] are

[Pd(NH_(3))_(2)(SCN)_(2)] and [Pd(NH_(3))_(2)(NCS)_(2)] are :

Type of isomerism which exists between [Pd(C_(6)H_(5))_(2)(SCN)_(2)] and [Pd(C_(6)H_(5))_(2)(NCS)_(2)] is :

The following isomers refer to [{(C_(6)H_(5))_"(3)"P}_(2)Pd(SCN)_(2)] and [{(C_(6)H_(5))_(3)P}_(3)Pd(NCS)_(2)]

Type of isomerism which exists between [Pd( C_6H_5)_2 (SCN)_2] and [Pd(C_6H_5)_2(NCS)_2] is

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-COORDINATION COMPOUNDS-Exercise 1
  1. The complexes [Co(NH(3))(6)][Cr(CN)(6)] and [Cr(NH(3))(6)][Co(CN)(6)] ...

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  2. Which can exist both as diastereoisomer and enantiomer ?

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  3. Due to the presence of ambidenate ligands coordination compounds show ...

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  4. EAN of Fe in [Fe(C(2)O(4))(3)]^(3-) is .

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  5. The correct IUPAC name of K(2)[Zn(OH)(4)] is

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  6. Match the Column and choose the correct option from the codes g...

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  7. The correct statement on the isomerism associated with the follow...

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  8. The compounds [PtCl(2)(CH(3))(4)]Br(2) and [PtBr(2)(NH(3))(4)]Cl(2) co...

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  9. Which of the following has an optical isomer? (en=ethylenediamine) ?

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  10. Which one amongst the following , exhibit geometrical isomerism ?

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  11. The correct name of the compound [Cu(NH(3))(4)](NO(3))(2), according t...

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  12. Which of the following ion does not follow EAN rule ?

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  13. A complex of the type [M(A A)(2)X(2)] is known to the optically active...

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  14. Optical isomerism is shown by octahedral complexes

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  15. The IUPAC name of [Ni (P Ph(3))(2) Cl(2) ]^(2+) is

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  16. Which one of the following has largest number of isomers?

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  17. IUPAC name of K(3)[Fe(CN)(6)] is

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  18. The number of water molecule(s) directly bonded to the metal centre in...

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  19. IUPAC name of Na(3)[Co(NO(2))(6)] is

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  20. Which kind of isomerism is exhibited by octahedral [Co(NH(3))(4)Br(2)]...

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