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Which kind of isomerism is exhibited by ...

Which kind of isomerism is exhibited by octahedral `[Co(NH_(3))_(4)Br_(2)]CI` ? .

A

Geometrical and ionisation

B

Geometrical and optical

C

optical ionisation

D

Geometrical only

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The correct Answer is:
A

Octahedral `[Co(NH_(3))_(4) Br_(2)]Cl` shows ionisation and geometrical isomerism
`[Co(NH_(3))_(4)Br_(2)]ClhArr[Co(NH_(3))_(4)Br_(2)]^(+)+Cl^(-)`
` [Co(NH_(3))_(4)BrClhArr[Co(NH_(3))_(4)BrCl]^(+)+Br^(-)`
in geometrical isomerism , coordination number of central metal atom (cobalt ) is six and shape is octahedral , so it shows following geoetrical isomers .
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