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Geometrical isomerism is shown by...

Geometrical isomerism is shown by

A

`[Ni(NH_(3))_(5)Br]^(+)`

B

`[Cr(NH_(3))_(4)(en)]^(3+)`

C

`[Co(en)_(3)]^(3+)`

D

`[Co(NH_(3))_(2)(en)_(2)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
D
Geometrical isomerism is exhibited by octahedral complexes , `[ Co (NH_(3))_(2) (en)_(2)]^(3+)` .
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Assertion (A) Complexes of MX_(6) and MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Reason (R) Geometrical isomerism is not shown by complexes of coordination number 6.

Statement-1: Complexes of MX_(6)" and "MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Statement-2: Geometrical isomerism is not shown by complexes of coordination number 6.

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-COORDINATION COMPOUNDS-Exercise 1
  1. The complex, [Pt(py)(NH3)BrCl] will have how many geometrical isomers?

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  2. The effective atomic is shown by

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  3. Geometrical isomerism is shown by

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  4. In which case EAN of Cr is maximum ?

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  5. Write IUPAC names of (i) K(3)[Fe(CN)(5)NO] (II) K(3)[Al(C(2)O(4))(3)...

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  6. The complex Na(2)[Fe(CN)(5)NO] is called :

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  7. Which of the following complexes show linkage isomerism ?

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  8. According to IUPAC nomenclature sodium nitroprusside is named as

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  9. The magnetic moment (spin only) of [NiCl4]^(2-) is

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  10. In Spectrochemical series , chorine is above than water . I .e ...

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  11. What is the magnetic moment of K(3)|FeF(6)| ?

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  12. The d-electron configurations of Cr^(2+), Mn^(2+), Fe^(2+) and Co^(2+)...

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  13. In which of the following coordination entites the magnitude of Delta(...

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  14. Which of the following complex species does not involve inner orbital ...

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  15. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1). The CFSE for...

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  16. Magnetic moment of the compledxes is zero in

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  17. For d^(4) ions the fourth electron enters one of the e(g ) ...

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  18. Which one of the following is wrongly matched ?

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  19. Which complex compound possesses sp^(3)d^(2) hybridization

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  20. The number of unpaired electrons in Ni (CO)(4) is

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