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Which of the following complex species d...

Which of the following complex species does not involve inner orbital hybridisation ?

A

`[CoF_(6)]^(3-)`

B

`[Co(NH_(3))_(6)]^(3+)`

C

`[Fe(CN)_(6)]^(3-)`

D

`[Cr(NH_(3))_(6)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
A

`[CoF_(6)]^(3-) ` is an outer orbital complex ion which has `SP_(3) d^(2)` - hybridisation because `F^(-)` is is a weak field ligand `[CoF_(6)]^(3-)`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-COORDINATION COMPOUNDS-Exercise 1
  1. The d-electron configurations of Cr^(2+), Mn^(2+), Fe^(2+) and Co^(2+)...

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  2. In which of the following coordination entites the magnitude of Delta(...

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  3. Which of the following complex species does not involve inner orbital ...

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  4. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1). The CFSE for...

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  5. Magnetic moment of the compledxes is zero in

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  6. For d^(4) ions the fourth electron enters one of the e(g ) ...

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  7. Which one of the following is wrongly matched ?

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  8. Which complex compound possesses sp^(3)d^(2) hybridization

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  9. The number of unpaired electrons in Ni (CO)(4) is

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  10. how many uppaired electrons are present in the central metal io...

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  11. Crystal field stabilization energy for high spin d^4 octahedral comple...

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  12. Magnetic moments 2.84 B.M is given by : (At. nos. ni = 28, Ti = 22, ...

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  13. [NiCl(4)]^(2-) is paramagnetic while [Ni(CO)(4)] is diamagnetic though...

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  14. The correct relationship between Delta (t) and Delta (0) is expr...

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  15. [Sc(H(2)O)(6)]^(3+) ion is

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  16. Excited state configuration of Mn^(2+) is

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  17. Considering H2O as a weak field ligand, the number of unpaired electro...

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  18. Of the following complex ions, which is diamagnetic in natures?

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  19. An octahedral complex is formed when hybrid orbitals of the following ...

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  20. High spin complex [FeCI(6)]^(3-) has th d-configuration

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