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Consider the following statements , ...

Consider the following statements ,
I. In coordination compounds , metals show two types of linkage ( valencies ) .
II. The primary valencies are normallt ionisable and are satisfied by negative ions.
the correct statement(s) is / are

A

only I

B

only II

C

both I and II

D

neither I nor II

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The correct Answer is:
To analyze the given statements regarding coordination compounds, let's break down the information step by step. ### Step 1: Understanding the Statements - **Statement I**: In coordination compounds, metals show two types of linkage (valencies). - **Statement II**: The primary valencies are normally ionizable and are satisfied by negative ions. ### Step 2: Evaluating Statement I - According to Werner's theory, coordination compounds indeed have two types of valencies: primary and secondary. - **Primary Valency**: This is related to the oxidation state of the metal and is satisfied by negative ions. - **Secondary Valency**: This relates to the coordination number of the metal and is satisfied by neutral or negative ligands. - **Conclusion for Statement I**: This statement is **correct**. ### Step 3: Evaluating Statement II - The primary valencies are indeed ionizable, meaning they can dissociate in solution. - They are satisfied by negative ions (anions) that balance the positive charge of the metal. - **Conclusion for Statement II**: This statement is also **correct**. ### Final Conclusion Both statements I and II are correct. ### Summary of the Solution - **Statement I**: Correct (Two types of valencies exist in coordination compounds). - **Statement II**: Correct (Primary valencies are ionizable and satisfied by negative ions).

To analyze the given statements regarding coordination compounds, let's break down the information step by step. ### Step 1: Understanding the Statements - **Statement I**: In coordination compounds, metals show two types of linkage (valencies). - **Statement II**: The primary valencies are normally ionizable and are satisfied by negative ions. ### Step 2: Evaluating Statement I - According to Werner's theory, coordination compounds indeed have two types of valencies: primary and secondary. ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-COORDINATION COMPOUNDS-Exercise2 (Miscellaneous Problems)
  1. Which among the following will be named as dibromidobis ( ethye...

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  2. Which of the following is a negatively charged bidentable ligan...

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  3. Consider the follwing complexes ion P,Q and R P =[FeF(6)]^(3-), Q=[V...

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  4. One mole of complex compound Co(NH3)5Cl3 gives 3 moles of ions on diss...

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  5. Co-ordination number of platinum in [Pt(NH(3))(4)Cl(2)]^(2+) ion is :

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  6. Ammonia gas does not evolve from the complex FeCl(2).4NH(3) B...

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  7. How many electrons are present in 3d - orbital of tetrahedral ...

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  8. The two isomers X and Y with the formula Cr(H(2)O)(5)ClBr were taken f...

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  9. Geometrical shapes of the complexes fromed by the reaction of Ni^(2+)...

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  10. Which of the following shell , form only outer orbital octahed...

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  11. In Fe(CO)(5) . the Fe- C bond possesses

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  12. What is the structural formula of lithium tetrahydrido aluminate

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  13. Which of the following can participate in linkage isomerism ?

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  14. The non -existant metal carbonyl among the following is

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  15. Consider the following statements , I. In coordination compound...

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  16. The name of is

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  17. Atomic number of Mn , Fe CO and Ni are 25,26,27 and 28 respec...

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  18. Which one of the following has a square planar geometry ?

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  19. Which one of the cyano complexes would exhibit the lowest valu...

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  20. The pair of compounds having metals in their highest oxidation ...

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