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A magnetic moment of 1.73 B.M. will be s...

A magnetic moment of 1.73 B.M. will be shown by one among the following:

A

`[Cu(NH_(3))_(4)]^(2+)`

B

`[Ni(CN)_(4)]^(2-)`

C

`TiCl_(4) `

D

`[CoCl_(6)]^(4-)`

Text Solution

Verified by Experts

The correct Answer is:
A

Magnetic moment `mu ` is is related with number of unpaired electrons as
`mu = sqrt(n(n+2))BM `
`(1.73)^(2) = n(n+2)`
On solving , n=1
thus the complex / compound having one unpaired electron exhibit a magnetic moment of `1.73 ` BM
in `[Cu (NH_(3))_(4) ]^(2+)`
` Cu^(2+)= [Ar] 3d^(9)` =
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