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Reaction of ROH with R'MgX produces...

Reaction of ROH with `R'MgX` produces

A

`RH`

B

R'H

C

`R-R`

D

`R'-R'`

Text Solution

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The correct Answer is:
B
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Carboxylic acid, although unreactive to alcohols, reacts in the presence of small amount of conc. H_2 SO_4 or with 2-3 % of HCl ? RCOOH + R'OH overset (H^(oplus)) hArr RCOOR' + H_2 O Which of the following statements is//are correct about the above reaction ? (I) This reaction is called Fischer esterification reaction. (II) The equilibrium is shifted to R.H.S if H_2 O is removed by azeotropic distillation with benzene. (III) The reaction of RCOCl and R'OH to give ester (RCOOR') is irreversible and more feasible than esterification of RCOOH . (IV) If the above esterification of RCOOH is carried out in excess of R'OH , the equilibrium is shifted to R.H.S .

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 1 (TOPICAL PROBLEMS))
  1. The order or reactivity of the following alcohols is

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  2. Which one of the following will most readily be dehydrated in acidic c...

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  3. Reaction of ROH with R'MgX produces

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  4. In which of the following molecules, the cleavage by HlO(4) is not obs...

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  5. Which of the following reactions is not reversible ?

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  6. Among the following ethers, which one will produce methyl alcohol on t...

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  7. Ester formation from CH(3)COOH takes place to maximum extent when alco...

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  8. C(4)H(10)O gives white precipitate immediately with conc. HCl in the p...

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  9. Which of the following combination can be used to synthesise ethanol?

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  10. The mechanism followed when the alcoholes given below reacts with conc...

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  11. Which of the following compounds can be used as antifreeze in automobi...

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  12. HCHO was treated with a reagent X. The product formed upon hydrolysis ...

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  13. Hydrolysis of alkyl halides has been compared. Which of the following ...

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  14. Alkene is also formed as the major product in the hydrolysis of which ...

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  15. Carbonyl compounds are reduced to alcohols by hydride reagents. This r...

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  16. CH(3)overset(O)overset(||)"CCH"(2)overset(O)overset(||)COCH(3) is redu...

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  17. During the dehydration of alcohols to alkenes by heating with conc. H(...

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  18. Which of the following alkenes will give same product by any method ou...

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  19. The product obtained on heating ethanol with conc. H(2)SO(4) at 165^(@...

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  20. Which of the following statement is incorrect?

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