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Among the following ethers, which one wi...

Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated `HI`?

A

`CH_(3)-CH_(2)-CH_(2)-CH_(2)-O-CH_(3)`

B

`CH_(3)-CH_(2)-underset(CH_(3))underset("| ")"CH"-O-CH_(3)`

C

`CH_(3)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-O-CH_(3)`

D

`CH_(3)-underset(CH_(3))underset("| ")"CH"-CH_(2)-O-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
C

The ether, which gives more stable carboncation, gives `CH_(3)OH` as one of the product with hot coccentrated `Hl`. The order of stability of carbocation is `3^(@)gt 2^(@) gt 1^(@)`
Thus, `{:(" "CH_(3)),(" |"),(CH_(3)-C-OCH_(3)),(" |"),(" "CH_(3)):}` gives `CH_(3)OH` as one of the products. The reaction proceeds as
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 1 (TOPICAL PROBLEMS))
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  2. Which of the following reactions is not reversible ?

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  4. Ester formation from CH(3)COOH takes place to maximum extent when alco...

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  5. C(4)H(10)O gives white precipitate immediately with conc. HCl in the p...

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  6. Which of the following combination can be used to synthesise ethanol?

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  7. The mechanism followed when the alcoholes given below reacts with conc...

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  8. Which of the following compounds can be used as antifreeze in automobi...

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  9. HCHO was treated with a reagent X. The product formed upon hydrolysis ...

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  10. Hydrolysis of alkyl halides has been compared. Which of the following ...

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  11. Alkene is also formed as the major product in the hydrolysis of which ...

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  12. Carbonyl compounds are reduced to alcohols by hydride reagents. This r...

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  13. CH(3)overset(O)overset(||)"CCH"(2)overset(O)overset(||)COCH(3) is redu...

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  14. During the dehydration of alcohols to alkenes by heating with conc. H(...

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  15. Which of the following alkenes will give same product by any method ou...

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  16. The product obtained on heating ethanol with conc. H(2)SO(4) at 165^(@...

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  17. Which of the following statement is incorrect?

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  18. Denatured alcohol is

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  19. Which is incorrect order for dehydration of alcohol ?

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  20. Which one of the following reagent can differentiate between C(2)H(4)O...

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