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Ester formation from CH(3)COOH takes pla...

Ester formation from `CH_(3)COOH` takes place to maximum extent when alcohol is

A

`CH_(3)OH`

B

`CH_(3)CH_(2)OH`

C

`(CH_(3))_(2)CHOH`

D

`(CH_(3))_(3)COH`

Text Solution

Verified by Experts

The correct Answer is:
A

As the size of the group R around `-COOH` in acids or that of R' around `-OH` in alcohols increases, the rate of the esterification reaction decreases.
Thus, in esterification reaction, the order of reactivity of alcohols follows the sequence.
`CH_(3)OH gt CH_(3)CH_(2)OH gt (CH_(3))_(2) CHOH gt (CH_(3))_(3)COH`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 1 (TOPICAL PROBLEMS))
  1. Which of the following reactions is not reversible ?

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  2. Among the following ethers, which one will produce methyl alcohol on t...

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  3. Ester formation from CH(3)COOH takes place to maximum extent when alco...

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  4. C(4)H(10)O gives white precipitate immediately with conc. HCl in the p...

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  5. Which of the following combination can be used to synthesise ethanol?

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  6. The mechanism followed when the alcoholes given below reacts with conc...

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  7. Which of the following compounds can be used as antifreeze in automobi...

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  8. HCHO was treated with a reagent X. The product formed upon hydrolysis ...

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  9. Hydrolysis of alkyl halides has been compared. Which of the following ...

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  10. Alkene is also formed as the major product in the hydrolysis of which ...

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  11. Carbonyl compounds are reduced to alcohols by hydride reagents. This r...

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  12. CH(3)overset(O)overset(||)"CCH"(2)overset(O)overset(||)COCH(3) is redu...

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  13. During the dehydration of alcohols to alkenes by heating with conc. H(...

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  14. Which of the following alkenes will give same product by any method ou...

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  15. The product obtained on heating ethanol with conc. H(2)SO(4) at 165^(@...

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  16. Which of the following statement is incorrect?

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  17. Denatured alcohol is

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  18. Which is incorrect order for dehydration of alcohol ?

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  19. Which one of the following reagent can differentiate between C(2)H(4)O...

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  20. The only alcohol that can be prepared by the indirect hydration of alk...

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