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For the following reaction, select the s...

For the following reaction, select the statement that best describes the situation
`RCH_(2)OH+"PCC"[C_(5)H_(5)NH^(+)ClCrO_(3)^(-)]rarr`

A

The alcohol is oxidised to an acid and the Cr(VI) is reduced

B

The alcohol is oxidised to an aldehyde and the Cr(VI) is reduced

C

The alcohol is reduced to an aldehyde and the Cr(III) is oxidised

D

The alcohol is oxidised to a ketone and the Cr(VI) is reduced

Text Solution

Verified by Experts

The correct Answer is:
B

`RCH_(2)OH+underset("(in PCC)")(Cr(VI))rarr R CHO +Cr(III)`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 1 (TOPICAL PROBLEMS))
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  2. Iodoform reaction is answered by all, except

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  3. For the following reaction, select the statement that best describes t...

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  4. Which product is obtained from the following esterification reaction ?...

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  5. Which of the following compounds is most acidic?

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  6. The -OH group of an alcohol or of the -COOH group of a carboxylic acid...

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  7. Primary, secondary and tertiary alcohols can be distinguished by perfo...

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  8. HBr reacts fastest with

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  9. CH(3)CH(2)OH convert into CH(3)CHO in the presence of

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  10. The order of melting point of ortho, para, meta nitrophenol is

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  11. When phenol is treated with D(2)SO(4)//D(2)O, some of the hydrogens ge...

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  12. Phenol is treated with bromine water and shaken well. The white precip...

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  13. Among the following sets of reactants which one produces anisole?

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  14. Phenol overset(X)rarr forms a tribromo derivative. X is

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  15. The product of the following reaction is

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  16. Phenol reacts with NH(3) to give

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  17. Which of the following reaction involves carbon-carbon bond formation?

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  18. Which of the following is most acidic ?

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  19. Correct acidic order of the following compounds is

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  20. Cumene process is the most important commercial method for the manufac...

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