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Phenol on treatment with diethyl sulphat...

Phenol on treatment with diethyl sulphate in presence of `NaOH` gives

A

phenetole

B

anisole

C

diphenyl ether

D

diethyl ether

Text Solution

Verified by Experts

The correct Answer is:
A

Diethyl sulphate in the presence of NaOH acts as alkylating agent, it causes alkylation of phenol to give ethyl phenyl ether which is also called phenetone.
`C_(6)H_(5)OH+NaOH rarr C_(6)H_(5)O^(-)Na^(+)+H_(2)O`
`C_(6)H_(5)O^(-)Na^(+)+underset("Diethyl sulphate")((C_(2)H_(5))SO_(4))rarr underset("Phenetole")(C_(6)H_(5)OC_(2)H_(5))+C_(2)H_(5)NaSO_(4)`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 1 (TOPICAL PROBLEMS))
  1. Sulphonation of phenol with conc. H(2)SO(4) at 288-298 K gives

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  2. Acidity of phenol is due to

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  3. Phenol on treatment with diethyl sulphate in presence of NaOH gives

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  4. By heating phenol with chloroform in alkali, it is converted into

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  5. C(2)H(5)OH and C(6)H(5)OH can be distinguished by

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  6. The most acidic compound is

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  7. Which of the following can be used to convert into phenol in one or mo...

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  8. Ortho and para-nitrophenols are separated by which of the following me...

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  9. The most unlikely representation of resonance structures of p-nitrophe...

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  10. The reaction used for the preparation of phenol is

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  11. Phenol can be distinguished from ethanol by the following reagents exc...

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  12. Phenol when it first reacts with concentrated sulphuric acid and then ...

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  13. Salicylaldehyde is obtained when phenol is heated with CHCl(3) and aqu...

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  14. Consider the following reaction Phenol overset(Zn)underset("dust")ra...

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  15. The major product in the above reaction is

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  16. Which one of the following properties is exhibited by phenol ?

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  17. Which of the following reactions will not yield p-tert butylphenol?

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  18. Phenol underset((ii) CO(2)//140^(@)C)overset((i)NaOH)rarrAoverset(H^(+...

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  19. The IUPAC name of m-cresol is

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  20. Phenol react with PCl(5) to give mainly

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