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Which of the following does not react wi...

Which of the following does not react with sodium metal ?

A

`(CH_(3))_(2)O`

B

`CH_(3)CH_(2)OH`

C

`CH_(3)COOH`

D

`C_(6)H_(5)OH`

Text Solution

Verified by Experts

The correct Answer is:
A

Only acidic compounds such as acetic acid, phenol and alcohol react with sodium metal. Ether is not acidic in nature, hence it does not react with sodium metal.
`{:(underset("Ethanol")(2CH_(3)CH_(2)OH)+2Na rarr underset("Sodium ethoxide")(2CH_(3)CH_(2)ONa)+H_(2)),(underset("Acetic acid")(2CH_(3)COOH)+2Na rarr underset("Sodium acetate")(2CH_(3)COONa)+H_(2)),(underset("Phenol")(2C_(6)H_(5)OH)+2Na rarr underset("phenoxide")underset("Sodium")(2C_(6)H_(5)ONa)+H_(2)),(CH_(3)-O-CH_(3)+Na rarr"No reaction"):}`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 1 (TOPICAL PROBLEMS))
  1. Which of the following reactions will not yield p-tert butylphenol?

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  2. Phenol underset((ii) CO(2)//140^(@)C)overset((i)NaOH)rarrAoverset(H^(+...

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  3. The IUPAC name of m-cresol is

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  4. Phenol react with PCl(5) to give mainly

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  5. The correct decreasing order of acid strength of the following compoun...

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  6. Phenol is soluble in water because

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  7. In the following reaction, X is identified as

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  8. A simple method to remove peroxides from ethers is to treat them with ...

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  9. The major product obtained when tert- butyl bromide is heated with sod...

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  10. Tert-butyl methyl ether on heating with anhydrous HI in ether gives

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  11. State the product formed during the reaction between sodium phenoxide ...

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  12. The bond angle in R-OR is

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  13. What are the products in the following reaction ? C(2)H(5)OC(2)H(5)o...

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  14. The reaction of with H(2)O and R-MgX produces

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  15. Which of the following does not react with sodium metal ?

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  16. Major additon product of the following reaction is

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  17. Formation of di ethyl ether form ethanol is based on a

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  18. The product obtained by heating diethyl ether with HI is

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  19. Ether is a good solvent for Grignard reagent. Which property makes it ...

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  20. Which of the following is the best method for making iso-propylmethyl ...

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