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Which of the following compounds is opti...

Which of the following compounds is optically active?

A

1-butanol

B

Isopropyl alcohol

C

Acetaldehyde

D

2-butanol

Text Solution

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The correct Answer is:
To determine which of the given compounds is optically active, we need to identify if any of the compounds contain a chiral carbon atom. A chiral carbon is one that is bonded to four different groups or atoms. Let's analyze each compound step-by-step: ### Step 1: Identify the Compounds We have four compounds to analyze: 1. **1-butanol** (Compound A) 2. **Isopropyl alcohol** (Compound B) 3. **Acetaldehyde** (Compound C) 4. **2-butanol** (Compound D) ### Step 2: Draw the Structures - **1-butanol**: CH3-CH2-CH2-CH2OH - **Isopropyl alcohol**: (CH3)2CHOH - **Acetaldehyde**: CH3CHO - **2-butanol**: CH3-CH(OH)-CH2-CH3 ### Step 3: Analyze Each Compound for Chirality 1. **1-butanol**: - The carbon atoms in 1-butanol are either bonded to two hydrogens or are part of a straight chain. None of the carbons are bonded to four different groups. Thus, it is **not optically active**. 2. **Isopropyl alcohol**: - The carbon atoms in isopropyl alcohol are also bonded to either two hydrogens or are part of a branched structure. There is no carbon bonded to four different groups. Thus, it is **not optically active**. 3. **Acetaldehyde**: - The carbonyl carbon in acetaldehyde is bonded to a methyl group (CH3), a hydrogen (H), and an oxygen (O). However, it is also bonded to another carbon (the carbonyl group), making it planar and not chiral. Thus, it is **not optically active**. 4. **2-butanol**: - The second carbon in 2-butanol is bonded to four different groups: a methyl group (CH3), an ethyl group (CH2-CH3), a hydroxyl group (OH), and a hydrogen (H). This carbon is chiral, making 2-butanol **optically active**. ### Conclusion Based on the analysis, the compound that is optically active is **2-butanol** (Compound D).

To determine which of the given compounds is optically active, we need to identify if any of the compounds contain a chiral carbon atom. A chiral carbon is one that is bonded to four different groups or atoms. Let's analyze each compound step-by-step: ### Step 1: Identify the Compounds We have four compounds to analyze: 1. **1-butanol** (Compound A) 2. **Isopropyl alcohol** (Compound B) 3. **Acetaldehyde** (Compound C) 4. **2-butanol** (Compound D) ...
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