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In the presence of dry HCl gas, CH(3)CHO...

In the presence of dry HCl gas, `CH_(3)CHO` condenses with `C_(2)H_(5)OH` to give

A

aldol

B

ethyl acetate

C

acetal

D

polymer

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AI Generated Solution

The correct Answer is:
To solve the problem of what compound is formed when acetaldehyde (CH₃CHO) condenses with ethyl alcohol (C₂H₅OH) in the presence of dry HCl gas, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are acetaldehyde (CH₃CHO) and ethyl alcohol (C₂H₅OH). 2. **Understand the Reaction Type**: This reaction is an example of acetal formation. Acetals are formed when a carbonyl compound (like an aldehyde) reacts with alcohol in the presence of an acid catalyst. 3. **Protonation of the Carbonyl Group**: In the presence of dry HCl, the carbonyl oxygen of acetaldehyde gets protonated, making the carbonyl carbon more electrophilic. This step can be represented as: \[ \text{CH}_3\text{CHO} + \text{H}^+ \rightarrow \text{CH}_3\text{C(OH)}^+ \text{H} \] 4. **Nucleophilic Attack by Ethanol**: The ethyl alcohol (C₂H₅OH) acts as a nucleophile and attacks the protonated carbonyl carbon, leading to the formation of a hemiacetal. This can be represented as: \[ \text{CH}_3\text{C(OH)}^+ \text{H} + \text{C}_2\text{H}_5\text{OH} \rightarrow \text{CH}_3\text{C(OH)(OC}_2\text{H}_5) \] 5. **Proton Transfer**: A proton transfer occurs within the hemiacetal, stabilizing the structure. This results in the formation of a hemiacetal intermediate. 6. **Formation of Acetal**: The hemiacetal can then react with another molecule of ethanol. The alcohol attacks the hemiacetal, leading to the formation of the acetal and the elimination of water: \[ \text{Hemiacetal} + \text{C}_2\text{H}_5\text{OH} \rightarrow \text{Acetal} + \text{H}_2\text{O} \] 7. **Final Structure of the Acetal**: The final product is diethyl acetal of acetaldehyde, which can be represented as: \[ \text{CH}_3\text{C(OC}_2\text{H}_5)_2 \] ### Final Answer: The compound formed is **Diethyl acetal of acetaldehyde** (or simply, **Acetal**).

To solve the problem of what compound is formed when acetaldehyde (CH₃CHO) condenses with ethyl alcohol (C₂H₅OH) in the presence of dry HCl gas, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are acetaldehyde (CH₃CHO) and ethyl alcohol (C₂H₅OH). 2. **Understand the Reaction Type**: This reaction is an example of acetal formation. Acetals are formed when a carbonyl compound (like an aldehyde) reacts with alcohol in the presence of an acid catalyst. ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MHT CET CORNER
  1. In the presence of dry HCl gas, CH(3)CHO condenses with C(2)H(5)OH to ...

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  2. Which of the following carboxylic acids is a tricarboxylic acid?

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  3. R-CNunderset(HCl)overset(SnCl(2))(to)" "overset(H(3)O^(o+))(to)R-C...

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  4. A mixture of benzaldehyde and formaldehyde on heating with aqueous NaO...

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  5. Which of the following compounds is most acidic in nature ?

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  6. Write the IUPAC name of following cmpound.

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  7. Identify to compound D in above mentioned series of reaction.

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  8. Which of the following reactions does not produce benzaldehyde as end ...

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  9. Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-meth...

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  10. Which of the following acids does not contain -COOH group ?

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  11. Aldol condensation product of acetone on dehydration gives

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  12. In the following reaction sequence, CH3CHO underset(Ca(OH)2)overset(Cl...

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  13. Among the following, the formula of saturated fatty acids is

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  14. Ethyl methyl ketone is obtained by heating calcium salts of

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  15. CH(3)COOH when reacts with C(2)H(2)OH gives a product. The same produc...

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  16. The IUPAC name of crotonaldehyde is

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  17. Which does not react with Fehling's solution?

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  18. Which of the acids cannot be prepared by Grignard reagent ?

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  19. Vinegar contains :

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  20. Vinegar is an aqueous solution of

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  21. The aldol condensationof acetaldehyde results in the formation of :

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