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A liquid was mixed with ethanol and a dr...

A liquid was mixed with ethanol and a drop of concentrated `H_(2) SO_(4)` was added. A compound with a fruity smell was formed. The liquid was

A

`CH_(3)OH`

B

`HCHO`

C

`CH_(3)COCH_(3)`

D

`CH_(3)COOH`

Text Solution

Verified by Experts

The correct Answer is:
D

A liquid `+C_(2)H_(5)OH overset("Conc". H_(2)SO_(4)) to underset(("Fruity smell"))("Compound")`
Fruity smell is the charactersitic property of ester thus reaction can be considered as follows.
`underset("Acetic acid") (CH_(3)COOH)+C_(2)H_(5)OH overset("Conc" H_(2)SO_(4)) to underset(("fruity smell"))underset("Ethyl acetate") overset(O) overset(||)(CH_(3)C-OC_(2))H_(5)+H_(2)O`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MHT CET CORNER
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  12. In the following reaction sequence, CH3CHO underset(Ca(OH)2)overset(Cl...

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