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What is obtained when nitrobenzene is tr...

What is obtained when nitrobenzene is treated sequesntially with (i) `NH_(4)Cl//Zn` dust and (ii) `H_(2)SO_(4)//Na_(2)Cr_(2)O_(7)`?

A

meta-chloronitrobenzene

B

para-chloronitrobenzene

C

nitrosobenzene

D

benzene

Text Solution

Verified by Experts

The correct Answer is:
C

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Explore conceptually related problems

(NH_(4))_(2)Cr_(2)O_(7) overset("heat") to

Na_(2)CrO_(4)+HCl to H_(2)Cr_(2)O_(7)+Na_(2)SO_(4)

Write the equations for the reaction of phenol with the following: (i) Br_(2) water (ii) CHCl_(3)+NaOH (iii) Na_(2)Cr_(2)O_(7)+Conc. H_(2)SO_(4) .

Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound , very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromite (FeCr_(2)O_(4)) ore according to the following reactions: (1) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4) + Na_(2)CO_(3) + O_(2) rarr Na_(2)CrO_(4)+Fe_(2)O_(3) +CO_(2) (2) Acidifing filtered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4) + H_(2)SO_(4) rarr Na_(2)Cr_(2)O_(7) + Na_(2)SO_(4) + H_(2)O (3) Treating sodium dichormate with potassium choride . Na_(2)Cr_(2)O_(7) + KCl rarr K_(2)Cr_(2)O_(7) + NaCl If the number of moles of reactant available for reaction are : [FeCr_(2)O_(4)=0.25 "moles" , O_(2)=0.35 "moles", Na_(2)CO_(3)=0.60 "moles", H_(2)SO_(4)=0.2 "moles", KCl=0.4 "moles"] , then the maximum number of moles of K_(2)Cr_(2)O_(7) , that can be produced is :

Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound , very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromite (FeCr_(2)O_(4)) ore according to the following reactions: (1) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4) + Na_(2)CO_(3) + O_(2) rarr Na_(2)CrO_(4)+Fe_(2)O_(3) +CO_(2) (2) Acidifing filtered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4) + H_(2)SO_(4) rarr Na_(2)Cr_(2)O_(7) + Na_(2)SO_(4) + H_(2)O (3) Treating sodium dichormate with potassium choride . Na_(2)Cr_(2)O_(7) + KCl rarr K_(2)Cr_(2)O_(7) + NaCl If whole of the chormite ore given in the previous question gets consumed and sufficient amount of rest of the reactants are given, then the mass of K_(2)Cr_(2)O_(7) obtained is:

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ORGANIC COMPOUNDS CONTAINING NITROGEN -MHT CET CORNER
  1. What is obtained when nitrobenzene is treated sequesntially with (i) N...

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  2. The amine 'A' when treated with nitrous acid gives yellow oily substan...

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  3. Which of the following will be most stable diazonium salt RN(2)^(+)Xba...

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  4. The replacement of diazonium group by fluorine is known as

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  5. R-C-=N+2H((i) SnCl(2)//"dil".HCl)/((ii)H(3)O^(+))RCHO + NH(4)Cl this ...

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  6. Diethyl amine when treated with nitrous acid yields

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  7. Identify the alkene that is produced in the following series of reacti...

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  8. An organic compound X having molecular formula C4H11N reacts with p-to...

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  9. Nitrobenzene on reaction with conc. (HNO3)/(H2SO4) at 80-100^@C forms ...

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  10. Some meta-directing substituents in aromatic substitution are given wh...

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  11. Which of the following is the strongest base?

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  12. In the following sequence of reactions CH-underset(NH(2))underset(|)...

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  13. In the following reaction sequence, CH3CHO underset(Ca(OH)2)overset(Cl...

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  14. Which of the following amines gives yellow oily liquid with HNO2 ?

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  15. N-ethyl-N-methylpropan-1-amine is

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  16. What is the end product in the following sequence of operations? C2 ...

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  17. The compound that forms a yellow oily liquid with nitrous acid is

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  18. Iso -propylamine is a

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  19. When acetamide is treated with Br(2) and caustic soda, then we get

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  20. On heating benzyl amine with chloroform and ethanolic KOH, product obt...

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  21. A mixture of ethyl amine and alcoholic KOH on heating gives

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