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In the chemical reaction, CH3CH2NH2 + CH...

In the chemical reaction, `CH_3CH_2NH_2 + CHCl_3 + 3KOH to A + B + 3H_2O`
The compounds A and B respectively are

A

`CH_3CH_2CONH_2` and 3KCl

B

`C_2H_5NC` and `K_2CO_3`

C

`C_2H_5NC` and `3KCl`

D

`C_2H_5CN` and 3KCl

Text Solution

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The correct Answer is:
To solve the reaction \( CH_3CH_2NH_2 + CHCl_3 + 3KOH \to A + B + 3H_2O \), we need to identify the products A and B formed in this reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: - Ethylamine (\( CH_3CH_2NH_2 \)) - Chloroform (\( CHCl_3 \)) - Potassium hydroxide (\( KOH \)) 2. **Recognize the Type of Reaction**: - This reaction is known as the **Carbylamine Reaction**. It is a characteristic reaction of primary amines with chloroform in the presence of a strong base (like KOH). 3. **Mechanism of the Reaction**: - The strong base \( KOH \) deprotonates the ethylamine, forming an ethylamine anion. - The ethylamine anion then reacts with chloroform to form a reactive intermediate called **dichlorocarbene**. 4. **Formation of Products**: - The dichlorocarbene reacts with the ethylamine to form an **alkyl isocyanide**. This is the compound A. - The other product formed in the reaction is **potassium chloride (KCl)**, which is compound B. 5. **Final Products**: - Therefore, the products of the reaction are: - A: Alkyl isocyanide (specifically, ethyl isocyanide, \( CH_3CH_2N \equiv C \)) - B: Potassium chloride (\( KCl \)) ### Conclusion: The compounds A and B respectively are: - A: Ethyl isocyanide (\( CH_3CH_2N \equiv C \)) - B: Potassium chloride (\( KCl \))

To solve the reaction \( CH_3CH_2NH_2 + CHCl_3 + 3KOH \to A + B + 3H_2O \), we need to identify the products A and B formed in this reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: - Ethylamine (\( CH_3CH_2NH_2 \)) - Chloroform (\( CHCl_3 \)) - Potassium hydroxide (\( KOH \)) ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ORGANIC COMPOUNDS CONTAINING NITROGEN -MHT CET CORNER
  1. In the chemical reaction, CH3CH2NH2 + CHCl3 + 3KOH to A + B + 3H2O ...

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  2. The amine 'A' when treated with nitrous acid gives yellow oily substan...

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  3. Which of the following will be most stable diazonium salt RN(2)^(+)Xba...

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  4. The replacement of diazonium group by fluorine is known as

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  5. R-C-=N+2H((i) SnCl(2)//"dil".HCl)/((ii)H(3)O^(+))RCHO + NH(4)Cl this ...

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  6. Diethyl amine when treated with nitrous acid yields

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  7. Identify the alkene that is produced in the following series of reacti...

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  8. An organic compound X having molecular formula C4H11N reacts with p-to...

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  9. Nitrobenzene on reaction with conc. (HNO3)/(H2SO4) at 80-100^@C forms ...

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  10. Some meta-directing substituents in aromatic substitution are given wh...

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  11. Which of the following is the strongest base?

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  12. In the following sequence of reactions CH-underset(NH(2))underset(|)...

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  13. In the following reaction sequence, CH3CHO underset(Ca(OH)2)overset(Cl...

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  14. Which of the following amines gives yellow oily liquid with HNO2 ?

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  15. N-ethyl-N-methylpropan-1-amine is

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  16. What is the end product in the following sequence of operations? C2 ...

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  17. The compound that forms a yellow oily liquid with nitrous acid is

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  18. Iso -propylamine is a

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  19. When acetamide is treated with Br(2) and caustic soda, then we get

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  20. On heating benzyl amine with chloroform and ethanolic KOH, product obt...

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  21. A mixture of ethyl amine and alcoholic KOH on heating gives

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