Home
Class 12
CHEMISTRY
In the given set of reactions : 2-"Bro...

In the given set of reactions :
`2-"Bromopropane " overset("alc.AgCN")underset(Delta)(to) 'X' overset(LiAIH_(4))(to) 'Y'`
The IUPAC name of product 'Y' is :

A

N-methylpropanamlne

B

N-isopropylmethanamine

C

Butan-2-amine

D

N-methylpropan-2-amlne

Text Solution

Verified by Experts

The correct Answer is:
D

`underset"2-bromopropane"(H_3C-underset"Br"underset|CH-CH_3) underset"alc./Heat"overset"AgCN"to underset"(X) isocyanide"(H_3C-undersetunderset(NC)|CH-CH_3)`
AgCN is mainly covalent in nature and nitrogen is free to · donate electron pair fqrming isocyanide as the main product.
`{:(H_3C-CH-CH_3 overset(LiAlH_4)to H_3C-CH-CH_3),(" |" " |" ),(" "NC " "HN-CH_3),(" "X" "underset"(N-methylpropan-2-amine)"Y):}`
Nitriles on reduction with lithium aluminium hydride ( `LiAIH_4`) produce amines.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|34 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|34 Videos
  • NATURE OF CHEMICAL BOND

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise EXERCISE 2 (Miscellaneous Problems)|20 Videos
  • P-BLOCK ELEMENTS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET corner|43 Videos

Similar Questions

Explore conceptually related problems

(CH_(3))_(3)C CI overset(alc.KOH)underset(Delta)rarr X overset(CF_(3)CO_(3)H)rarr Y The product 'Y' is

What is the end product (B ) in the following reaction sequence ? "Butanamide " overset(P_(2) O_(5))underset(Delta)(to) A overset(LiAIH_(4))(to)B

Acetone overset(NH_(2)OH)rarr X overset(LiAIH_(4))rarr Y . In the above sequence Y is

Consider the following sequence of reactions underset(base)overset(CH_(3)COCI)rarrA underset(2.H_(2)O)overset(1.LiAIH_(4),ether)rarrB The end product B is .

In the given reaction : Ph-underset(O)underset(||)C-CHY_(3)overset(H_(2)N-OH)rarr(X) underset(Delta)overset(PCI_(5))rarr(Y) Y will be

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ORGANIC COMPOUNDS CONTAINING NITROGEN -EXERCISE 2 (MISCELLANEOUS PROBLEMS )
  1. Which of the following compounds reacts slower than benzene in eleetro...

    Text Solution

    |

  2. In the given set of reactions : 2-"Bromopropane " overset("alc.AgCN"...

    Text Solution

    |

  3. Aromatic primary amines can be distinguished from aliphatic primary am...

    Text Solution

    |

  4. Considering the basec strength of amines in aqueous solution which one...

    Text Solution

    |

  5. The reagent with which the following reaction is best accomplished is

    Text Solution

    |

  6. An organic compound (C3H9N) (A) when treated with nitrous acid , gave ...

    Text Solution

    |

  7. In the reaction,

    Text Solution

    |

  8. RCONH(2)+4NaOH+Br(2) to RNH(2) + 2NaBr+Na(2)CO(3)+2H(2)O Reaction is s...

    Text Solution

    |

  9. Compound A (C(3)H(9)N) reacts with benzene sulphonyl chloride to form ...

    Text Solution

    |

  10. Match the reactant in Column I with the reaction in Column II

    Text Solution

    |

  11. Consider the following reaction The compound B is

    Text Solution

    |

  12. Which of the following amides will not undergo Hofmann bromamide react...

    Text Solution

    |

  13. Which of the following is the strongest base:

    Text Solution

    |

  14. Aniline when diazotiesd in cold and then treated with dimethy1 aniline...

    Text Solution

    |

  15. Which compound exhibits maximum dipole moment among the following ?

    Text Solution

    |

  16. Aniline is treated wi.th bromine water to give an organic compound X w...

    Text Solution

    |

  17. Which of the following compounds does liberate CO2 from NaHCO3?

    Text Solution

    |

  18. Nitrobenzene can be prepared from benzene by using a mixture of cone. ...

    Text Solution

    |

  19. Match the amines given in Column I with their classification in the Co...

    Text Solution

    |

  20. In the given reaction, NH3+RX to underset((1^@))(R NH2)+RX to underset...

    Text Solution

    |