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Which of the following is the strongest ...

Which of the following is the strongest base:

A

`C_6H_5NH_2`

B

`p-NO_2-C_6H_5NH_2`

C

`m-NO_2-C_6H_5NH_2`

D

`C_6H_5CH_2NH_2`

Text Solution

Verified by Experts

The correct Answer is:
D
Aliphatic amines (in which amino group is attached with alkyl group) are more basic than aromatic amines (in which amino group is bonded directly with benzene nucleus). Hence, `C_6H_5CH_2NH_2` (benzyl amine), being an aliphatic amine, is the most basic among the given compounds.
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ORGANIC COMPOUNDS CONTAINING NITROGEN -EXERCISE 2 (MISCELLANEOUS PROBLEMS )
  1. Consider the following reaction The compound B is

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  2. Which of the following amides will not undergo Hofmann bromamide react...

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  3. Which of the following is the strongest base:

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  4. Aniline when diazotiesd in cold and then treated with dimethy1 aniline...

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  5. Which compound exhibits maximum dipole moment among the following ?

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  6. Aniline is treated wi.th bromine water to give an organic compound X w...

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  7. Which of the following compounds does liberate CO2 from NaHCO3?

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  8. Nitrobenzene can be prepared from benzene by using a mixture of cone. ...

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  9. Match the amines given in Column I with their classification in the Co...

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  10. In the given reaction, NH3+RX to underset((1^@))(R NH2)+RX to underset...

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  11. Arrange the following compounds in increasing order of their acidic st...

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  12. Which of the following reaction/statement is incorrect?

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  13. In the following reaction, What is X and Y in the above reaction?

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  14. The correct reaction for Hofmann mustard oil reaction is

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  15. Identify A and Bin the following reaction.

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  16. The best reagent for converting 2-phenylpropanamide into 2-phenylpropa...

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  17. What are the constituent amines formed when the mixture of (1) and (2)...

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  18. Consider the following reaction sequence . The final product of this r...

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  19. Primary amine is not formed in the reaction of I. hydrolysis of RCN...

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  20. Arrange the following in the decreasing order of pKb values I. C2H5N...

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