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Arrange the following compounds in incre...

Arrange the following compounds in increasing order of their acidic strength:
(i) m-nitrophenol (ii) m-cresol
(iii) phenol (iv) m-chlorophenol

A

`III lt II lt I lt IV`

B

`II lt IV lt III lt I`

C

`II lt III lt IV lt I`

D

`II lt III lt I lt IV`

Text Solution

Verified by Experts

The correct Answer is:
C


m-cresol has an electron releasing group `(CH_3)`. Hence, it decreases the acidic strength.Both nitro and chloro are having -I effect. Hence, they show higher acidic strength . But nitro is a stronger -I group than chloro group . Hence, m-nitro phenol is more acidic than m-chlorophenol So increasing order of acidic strength is II lt III lt IV lt I .
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