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CHCl(3) and KOH on heating with a compo...

`CHCl_(3)` and KOH on heating with a compound form a bad smelling product compound is

A

`C_2H_5CN`

B

`C_2H_5NC`

C

`C_2H_5OH`

D

`C_2H_5NH_2`

Text Solution

Verified by Experts

The correct Answer is:
D
This is carbylamine reaction which is used to distinguish `1^@` amines from other amines . The reaction is given by `1^@` amines only.
`C_2H_5NH_2 + CHCl_3 + 3KOH to C_2H_5N undersetto= C + 3KCl + 3H_2O`
`underset(1^@ "amine")(RNH_2) + underset"Chloroform"(CHCl_3) + 3KOH to underset"(bad smelling)"underset"Isocyanide"(RN undersetto=C)+3KCl + 3H_2O`
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ORGANIC COMPOUNDS CONTAINING NITROGEN -EXERCISE 2 (MISCELLANEOUS PROBLEMS )
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