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C2H5NH2 overset(HNO2)to A overset(PCl5)t...

`C_2H_5NH_2 overset(HNO_2)to A overset(PCl_5)to B overset(NH_3)to C `
The compound C is identified as

A

acetamide

B

ethylamine

C

ethyl cyanide

D

methyl amine

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The correct Answer is:
To solve the problem step by step, we will analyze the reactions that occur when ethylamine (C2H5NH2) is treated with HNO2, PCl5, and NH3. ### Step 1: Reaction of Ethylamine with HNO2 - **Reaction**: Ethylamine (C2H5NH2) is treated with nitrous acid (HNO2). - **Process**: This reaction leads to the formation of a diazonium salt. However, since ethylamine is a primary amine, the diazonium salt formed is unstable and will undergo hydrolysis. - **Product A**: The hydrolysis of the diazonium salt results in the formation of ethanol (C2H5OH). ### Step 2: Reaction of Ethanol with PCl5 - **Reaction**: The ethanol (C2H5OH) is then treated with phosphorus pentachloride (PCl5). - **Process**: PCl5 is used to convert the alcohol (OH group) into an alkyl halide (Cl group). The chlorine atom replaces the hydroxyl group. - **Product B**: The product of this reaction is ethyl chloride (C2H5Cl). ### Step 3: Reaction of Ethyl Chloride with Ammonia - **Reaction**: Ethyl chloride (C2H5Cl) is treated with ammonia (NH3). - **Process**: In this step, ammonia acts as a nucleophile and attacks the carbon atom bonded to the chlorine atom in ethyl chloride. This is an SN2 reaction where the chlorine atom is displaced. - **Product C**: The final product after the reaction with ammonia is ethylamine (C2H5NH2). ### Final Answer The compound C is identified as **Ethylamine (C2H5NH2)**. ---

To solve the problem step by step, we will analyze the reactions that occur when ethylamine (C2H5NH2) is treated with HNO2, PCl5, and NH3. ### Step 1: Reaction of Ethylamine with HNO2 - **Reaction**: Ethylamine (C2H5NH2) is treated with nitrous acid (HNO2). - **Process**: This reaction leads to the formation of a diazonium salt. However, since ethylamine is a primary amine, the diazonium salt formed is unstable and will undergo hydrolysis. - **Product A**: The hydrolysis of the diazonium salt results in the formation of ethanol (C2H5OH). ### Step 2: Reaction of Ethanol with PCl5 ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ORGANIC COMPOUNDS CONTAINING NITROGEN -EXERCISE 2 (MISCELLANEOUS PROBLEMS )
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  2. Consider the following sequence Product of this reaction is

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  3. The best reagent for converting, 2-phenylpropanamide into 1-phenyletha...

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  4. The reaction of chloroform with alcoholic KOH and p-toluidine form-

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  5. Give the structure of A in the following reaction.

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  6. What is the end-product of the following reaction?

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  7. Following 1^@ amine has chiral carbon as indicated H-undersetunders...

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  8. C4H11N on reaction with HNO2 forms tertiary alcohol . Thus , C4H11N is

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  9. Aniline can be converted to benzene by

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  10. C2H5NH2 overset(HNO2)to A overset(PCl5)to B overset(NH3)to C The co...

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  11. The producr obtained is the following reaction is Aniline+ excess o...

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  12. N-methyl aniline on reaction with nitrous acid gives

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  13. In the reaction shown below, the major product(s) formed is/are

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  14. The reaction of aniline with chloroform under alkaline conditions lead...

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  15. Consider the following sequence of reaction. C6H5NH2 underset(HCl)o...

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  16. The product formed by the reaction of acetamide with bromine in presen...

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  17. Which of the following will be most stable diazonium salt RN(2)^(+)Xba...

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  18. In the given reaction , The product A is

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  19. N-butylamine (I), diethylamine (II) and N,N-dimethyl ethylamine(III) h...

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  20. The strongest base among the following is

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