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N-methyl aniline on reaction with nitrou...

N-methyl aniline on reaction with nitrous acid gives

A

N-nitroso-N-methylaniline

B

p-nitroso-N-methylaniline

C

p-nitro-N-methylaniline

D

N-nitro-N-methylaniline

Text Solution

Verified by Experts

The correct Answer is:
A
`C_6H_5 - NH- CH_3 + HONO to underset"N-nitroso-N-methyl aniline"(C_6H_5 - undersetunderset(NO)|N-CH_3+H_2O)`
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1 mole of methylamine on reaction with nitrous acid gives at NTP:

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Knowledge Check

  • 1 mole of methylamine on reaction with nitrous acid gives at NTP:

    A
    1 litre of nitrogen
    B
    22.4 litre of nitrogen
    C
    11.2 of nitrogen
    D
    5.6 litre of nitrogen

  • 1 mole of methyl amine on reaction with nitrous acid at NTP gives

    A
    1 L of nitrogen
    B
    11.2 L of nitrogen
    C
    22.4 L of nitrogen
    D
    5.6 L of nitrogen

  • Statement 1: N, N-dimethyl aniline does not react with nitrous acid, whereas aniline react with nitrous acid. and Statement 2:N, N-dimethy aniline is more basic than aniline.

    A
    Statement-1 is true, Statement-2 is true, statement-2 is a correct explanation for statement-4
    B
    Statement-1 is true, statement-2 is true, statement-2 is not a correct explanation for statement-4
    C
    Statement-1 is true, statement-2 is False
    D
    Statement-1 is False, Statement-2 is True.
    • MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ORGANIC COMPOUNDS CONTAINING NITROGEN -EXERCISE 2 (MISCELLANEOUS PROBLEMS )
    1. Name the product formed when aniline reacts with carbonyl chloride in ...

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    2. Consider the following sequence Product of this reaction is

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    3. The best reagent for converting, 2-phenylpropanamide into 1-phenyletha...

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    4. The reaction of chloroform with alcoholic KOH and p-toluidine form-

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    5. Give the structure of A in the following reaction.

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    6. What is the end-product of the following reaction?

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    7. Following 1^@ amine has chiral carbon as indicated H-undersetunders...

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    8. C4H11N on reaction with HNO2 forms tertiary alcohol . Thus , C4H11N is

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    9. Aniline can be converted to benzene by

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    10. C2H5NH2 overset(HNO2)to A overset(PCl5)to B overset(NH3)to C The co...

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    11. The producr obtained is the following reaction is Aniline+ excess o...

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    12. N-methyl aniline on reaction with nitrous acid gives

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    13. In the reaction shown below, the major product(s) formed is/are

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    14. The reaction of aniline with chloroform under alkaline conditions lead...

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    15. Consider the following sequence of reaction. C6H5NH2 underset(HCl)o...

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    16. The product formed by the reaction of acetamide with bromine in presen...

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    17. Which of the following will be most stable diazonium salt RN(2)^(+)Xba...

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    18. In the given reaction , The product A is

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    19. N-butylamine (I), diethylamine (II) and N,N-dimethyl ethylamine(III) h...

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    20. The strongest base among the following is

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