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What is Frenkl defect ?...

What is Frenkl defect ?

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Frenkl defect :
1) It is a point defect in which an atom or ion is shifted from its normal lattice position. The ion or the atom now occupies an interstitial position in the lattice .
2) This type of a defect is favoured by a large difference in sizes between the cation and anion . In these compounds co-ordination number is low .
E.g. : Ag - halides , ZnS etc.
3) Illustration :

4) Frenkel defect do not change the density of the solids significantly .
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Explain the following terms with suitable examples: (i) Schottky defect (ii) Frenkel defect (iii) Interstitials and (iv) F-centres.

What is Schottky defect ?

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(A) Schottky and Frenkel defects are also called thermodynamic defects (R) Both Schottky and Frenkel defects increases with increase in temperature.

(A) Crystals exhibiting Frenkel type defects do not show any change in density due to defect (R) In Frenkel defect the interstitial cations and cation vacancies are equal in number

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  13. What is Frenkl defect ?

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  14. What is interstitial defect ?

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  15. What are f-centers ?

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