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What do you mean by activity and selecti...

What do you mean by activity and selectivity of catalyst ?

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Activity :
The ability of a catalyst in increasing the rate of reaction is defined as activity of catalyst.
`to` The activity of a catalyst depends upon the strength of chemisorption to a large extent .
`to` The reactions must get adsorbed reasonably strongly on to the catalyst to become reactive .
Eg : The catalystic activity increases from Group -5 to Group-11 for hydrogenation reactions.
The maximum activity being shown by 7-9 group metals.
`2H_(2_((g))) + O_(2_((g))) overset(Pt_((s)))to 2H_(2)O_((l))`
Selectivity :
The selectivity of a catalyst is its ability of direct a reaction to form specific products . The followign reactions indicate the selectivity of heterogeneous catalysis.
`to` Starting with `H_(2)` and CO, and using differnet catalysts, we get different products.
`CO_((g)) + 3H_(2_((g))) overset(Ni_((s)))to CH_(4_((g))) + H_(2)O_((g))`
`CO_((g))+2H_(2_((g))) underset(ZnO-Cr_(2)O_(3))overset(Cu_((s)))to CH_(3)OH_((g))`
`CO_((g))+H_(2_((g))) overset(Cu_((s))) to HCHO_((g))`
The action of a catalyst is highly selective in nature. A substance which acts as catalyst in one reaction any fail to catalyse another reaction.
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-SURFACE CHEMISTRY-SHORT ANSWER QUESTIONS
  1. Discuss the factors that influence the catalytic activity of enxymes.

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  2. Name any six enzyme catalysed reaction.

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  3. What do you mean by activity and selectivity of catalyst ?

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  4. How are colloids classified on the basis of physical states of compone...

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  5. How are colloids classified on the basis of nature of the dispersion ...

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  6. How are colloids classified on the basis of interaction between dispe...

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  7. What is the difference between a colloidal sol, get, emulsion and a fo...

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  8. What are lyophilic and lyophobic sols ? Give one example for each type...

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  9. Name a substance whose molecules consist of lyophilic as well as lyoph...

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  10. Describe Bredig's arc method of preparation of colloids with a neat di...

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  11. Name any four examples of preparation of colloids by chemical methods ...

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  12. Describe the purification of colloidal solution by the phenomenon of d...

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  13. Explain the formation of micelles with a neat sketch.

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  14. Action of soap is due to emulsification and micelle formation. Comment...

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  15. Explain the phenomenon of Brownian movement giving reasons for the occ...

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  16. Name the four positively charged sols.

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  17. Name the four negatively charged sols.

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  18. Explain the terms helmholtz electrical double layer and zeta potential...

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  19. Explain with a neat sketch the phenomenon of electrophoresis.

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  20. What is electrophoresis ?

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