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Why is the extraction of copper form pyr...

Why is the extraction of copper form pyries more difficult then that from its oxide ore through reduction?

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The extraction of copper from pyrites is more difficult than that from its oxide ore through reduction.
Explanation :
Pyrites `(Cu_(2)S)` cannot be reduced by carbon (or) hydrogent because the standard free energy of formation `(DeltaG^(@))` of `Cu_(2)S`is greater then those of `CS_(2)` and `H_(2)S`.
`{:(2Cu_(2)S+Crarr4Cu+CS_(2)),(Cu_(2)S+H_(2)rarrCu+H_(2)S):}}" Not feasible"`
`rarr` The `DeltaG^(@)` of copper oxide is less than that of `CO_(2)`.
`therefore`The sulphide ore is first converted to oxide by roasting and then reduced.
`2Cu_(2)S+3O_(2)underset("heat")overset("Roasting")rarr2Cu_(2)O+2SO_(2)`
`2Cu_(2)O+Crarr4Cu+CO_(2)["feasible"]`.
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Copper is the most moble of first row transition meals and occurs in small deposits in several countries ares of copper include chalcanthite (CuSO_(4)5H_(2)O) , afecamie (CuCHOH)_(3)) , cuprite (Cu_(2)O) Copper glance (Cu_(2)S) and rolachite (Cu_(2)(OH)_(2)CO_(3)) . However, 80% of the world copper production comes from the ore chalcopyrite (CuFeS_(2)) . The extraction of copper from chalopyrite in polves partial roasting, removal of Iron self-reduction. In sell reduction the reducing species is

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Copper is the most moble of first row transition meals and occurs in small deposits in several countries ares of copper include chalcanthite (CuSO_(4)5H_(2)O) , afecamie (CuCHOH)_(3)) , cuprite (Cu_(2)O) Copper glance (Cu_(2)S) and rolachite (Cu_(2)(OH)_(2)CO_(3)) . However, 80% of the world copper production comes from the ore chalcopyrite (CuFeS_(2)) . The extraction of copper from chalopyrite in polves partial roasting, removal of Iron self-reduction. Partial Roasting of chalcopyrite produces

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