Home
Class 12
CHEMISTRY
Indicate the types of isomerism exhibite...

Indicate the types of isomerism exhibited by the follow complexes and draw the structures for these isomers :
`[Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2)`

Text Solution

Verified by Experts

`[Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2):` it can exist as a pair of ionization isomers as well as linkage
Ionization isomers :
`[Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2) and [Co(NH_(3))_(5)(NO_(3))(NO_(2))(NO_(3))` as they give different ions on ionization.
`[Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2) overset("Ionization")rarr[Co(NH_(3))_(5)(NO_(2))]^(2+) +2NO_(3)^(-)`
`[Co(NH_(3))_(5)(NO_(3))](NO_(2))(NO_(3)) overset(" Ionization")rarr[Co(NH_(3))_(5)NO_(3)]^(2+) +NO_(2)^(-) +NO_(3)^(-)`
Linkage isomers : `[Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2) and [Co(NH_(3))_(5) ONO](NO_(3))_(2)`
Promotional Banner

Topper's Solved these Questions

  • D AND F- BLOCK ELEMENTS AND CO-ORDINATION COMPOUNDS

    VIKRAM PUBLICATION ( ANDHRA PUBLICATION)|Exercise LONG ANSWER QUESTIONS|23 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    VIKRAM PUBLICATION ( ANDHRA PUBLICATION)|Exercise Intex questions|5 Videos
  • ELECTROCHEMISTRY & CHEMICAL KINETICS

    VIKRAM PUBLICATION ( ANDHRA PUBLICATION)|Exercise DAM SURE|18 Videos

Similar Questions

Explore conceptually related problems

Indicate the types of isomerism exhibited by the follow complexes and draw the structures for these isomers : [Co(en)_(3)]Cl_(3)

Indicate the types of isomerism exhibited by the follow complexes and draw the structures for these isomers : [Pt(NH_(3))(H_(2)O)Cl_(2)]

Indicate the types of isomerism exhibited by the follow complexes and draw the structures for these isomers : K[Cr(H_(2)O)_(2)(C_(2)O_(4))_(2)]

What type of isomerism is exhibited by the complex (Cr(gly)_3) ?

Draw structures of geometrical isomers of [Fe(NH_(3))_(2)(CN)_(4)]^(-)

The number of geometrical isomers of [Co(NH_(3))_(3)(NO_(3))_(3)] is

The types of isomerism exhibited by [Co(NH_3)_5(NO_2)](NO_3)_2 is

No. of isomers of [Co(NH_(3))_(2)Cl_(2)(en)]^(+) are

Write the structures of the following (a)N_(2)O and (b) NO_(2)

VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-D AND F- BLOCK ELEMENTS AND CO-ORDINATION COMPOUNDS -INTEXT QUESTIONS
  1. Write the formulae for the follow Co-ordination compounds Amminebrom...

    Text Solution

    |

  2. Write the formulae for the follow Co-ordination compounds Dichlorido...

    Text Solution

    |

  3. Write the IUPAC names of the follow Co-ordination compounds. [Co(NH(...

    Text Solution

    |

  4. Write the IUPAC names of the follow Co-ordination compounds. [Co(NH(...

    Text Solution

    |

  5. Write the IUPAC names of the follow Co-ordination compounds. K(3)[Fe...

    Text Solution

    |

  6. Write the IUPAC names of the follow Co-ordination compounds. K(3)[Fe...

    Text Solution

    |

  7. Write the IUPAC names of the follow Co-ordination compounds. K(2)[Pd...

    Text Solution

    |

  8. Write the IUPAC names of the follow Co-ordination compounds. [Pt(NH(...

    Text Solution

    |

  9. Indicate the types of isomerism exhibited by the follow complexes and ...

    Text Solution

    |

  10. Indicate the types of isomerism exhibited by the follow complexes and ...

    Text Solution

    |

  11. Indicate the types of isomerism exhibited by the follow complexes and ...

    Text Solution

    |

  12. Indicate the types of isomerism exhibited by the follow complexes and ...

    Text Solution

    |

  13. Give evidence that [Co(NH(3))(5)Cl]SO(4) and [Co(NH(3))(5)SO(4)]Cl are...

    Text Solution

    |

  14. Explain on the basis of valence bond theory that [Ni(CN)(4)]^(2-) ion ...

    Text Solution

    |

  15. [NiCl(4)]^(2-) is paramagnetic while [Ni(CO)(4)] is diamgnetic though ...

    Text Solution

    |

  16. [Fe(H(2)O)(6)]^(3+) is strongly paramagnetic whereas [Fe(CN)(6)]^(3-) ...

    Text Solution

    |

  17. Why [Co(NH3)6]^(3+) is an inner orbital complex where is [Ni(NH3)6]^(...

    Text Solution

    |

  18. Predict the number of unpaired electrons in the square planar [Pt(CN)(...

    Text Solution

    |

  19. The hexaquo manganese (II) ion contains five unpaired electrons, while...

    Text Solution

    |

  20. Calculate the overall complex dissociation equilibrium constant for th...

    Text Solution

    |