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Explain SN^(2) reaction...

Explain `SN^(2)` reaction

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Nucleophilic Bimolecular substitution Reaction `S_(N) 2` :
1) The nucleophilic substitution reaction in which rate depends upon concentration of both reactants is called `S_(N) 2` reaction .
2) It follows `2^(nd)` order kinetics . So it is called bimolecular reaction .
Eg : Methyl chloride reacts with hydroxide ion and forms methanol and chloride ion.
3) Here the rate of reaction depends upon the concentration of two reactants .

4) In the above mechanism the configuration of carbon atom under attack inverts in much the same way as an umbrella is turned inside out when caught in a strong wind . This process is called inversion of configuration .
5) In transition state the carbon atom is simultaneously bonded to the incoming nucleophile and out going group . it is very unstable .
6) The order of reactivity for `S_(N) 2` reactions follows :
`1^(@)`-alkyl halides `gt 2^(@)`-alkyl halides `gt 3^(@)` - alkyl halides .
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-HALOALKANES AND HALOARENES-LONG ANSWER QUESTIONS
  1. Write the structures of the following organic halides . 1-Bromo-4 se...

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  2. Discuss the physical properties of haloalkanes .

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  3. Explain SN^(2) reaction

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  4. Explain why allylic and benzylic halides are more reactive towards S(N...

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  5. Describe the stereo chemical effect on the hydrolysis of 2-bromobutane...

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  6. What is the criteria for optical activity . Give two examples of chira...

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  7. Define Racemic mixture

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  8. Define Retention of configuration

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  9. Define Enantiomers .

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  10. Write the mechanism of dehydrohalogenation of 2-bromobutane .

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  11. Explain the Grignard reagents preparation and application with suitabl...

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  12. A primary alkyl halide C(4)H(9) Br (A) reacted with alcoholic KOH to g...

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  13. Account for the statements : Arylhalides are extremely less reactive...

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  14. Account for the statements : p-Nitrochlorobenzene and o,p-dinitrochl...

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  15. Explain how the conversions are carried out : Propene to Propanol

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  16. Explain how the conversions are carried out : Ethanol to But-1-yne

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  17. Explain how the conversions are carried out : 1-Bromopropane to 2-Br...

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  18. Explain how the conversions are carried out : Aniline to chlorobenze...

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  19. What happen when n-butylchloride is treated with alc. KOH.

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  20. What happen when Bromobenzene is treated with Mg in presence of dry ...

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