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What is the criteria for optical activit...

What is the criteria for optical activity . Give two examples of chiral molecules .

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Optical activity : The property of rotating the plane polarized light by a chemical substance is called optical activity .
`to` If the plane polarised light rotates in clock wise direction then it is dextro rotatory [(+) (or) d-forms].
`to` If the plane polarised light rotates in anti-clock wise direction condition then it is laevo rotatory [(-) or l-form] .
Crieteria for optical activity :
1) Chirality (or) dissymmetry is the necessary and sufficient condition for a molecule to show optical activity .
Chirality : The object which are non-superimposable on their mirror images are said to be chiral and this property is known as chirality .
2) Asymmetry (absence of symmetry) of the molecule is responsible for the optical activity of organic compounds .
Examples of chiral molecules :
i) 2-Butanol (ii) 2-Chlorobutane iii) 2-Bromopropanic acid .
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-HALOALKANES AND HALOARENES-LONG ANSWER QUESTIONS
  1. Explain SN^(2) reaction

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  2. Explain why allylic and benzylic halides are more reactive towards S(N...

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  3. Describe the stereo chemical effect on the hydrolysis of 2-bromobutane...

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  4. What is the criteria for optical activity . Give two examples of chira...

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  5. Define Racemic mixture

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  6. Define Retention of configuration

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  7. Define Enantiomers .

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  8. Write the mechanism of dehydrohalogenation of 2-bromobutane .

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  9. Explain the Grignard reagents preparation and application with suitabl...

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  10. A primary alkyl halide C(4)H(9) Br (A) reacted with alcoholic KOH to g...

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  11. Account for the statements : Arylhalides are extremely less reactive...

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  12. Account for the statements : p-Nitrochlorobenzene and o,p-dinitrochl...

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  13. Explain how the conversions are carried out : Propene to Propanol

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  14. Explain how the conversions are carried out : Ethanol to But-1-yne

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  15. Explain how the conversions are carried out : 1-Bromopropane to 2-Br...

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  16. Explain how the conversions are carried out : Aniline to chlorobenze...

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  17. What happen when n-butylchloride is treated with alc. KOH.

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  18. What happen when Bromobenzene is treated with Mg in presence of dry ...

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  19. What happen when Methylbromide is treated with sodium in presence of...

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  20. Write the reactions showing the major and minor product when chloroben...

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