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Explain the role of electron withdrawing...

Explain the role of electron withdrawing and electron releasing groups on the acidity of carboxylic acids.

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`to` Electron with drawing groups increase the acidity of carboxylic acids by stabilising the conjugate base through decocalisation of the negative charge by inductive effect.
`to` electron donating groups decreases the acidity of carboxylic acids by destabilising the conjugate base.

Eg : `Cl^(-)` is a electron with drawing group acidic stregnth order in case of chloro acetic acids `"CC"l_(3)COOH gt CHCl_(2)COOH gt CH_(2)ClCOOH gt CH_(3)COOH`
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VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-ORGANIC COMPOUNDS CONTAINING C,H AND O-SHORT ANSWER QUESTIONS
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  2. Describe the Decarboxylation.

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  5. Draw the structure of the ethylene ketal of hexan-3-one.

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  6. Draw the structure of the methyl hemiacetal of formaldehyde.

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  7. An organic compound contains 69.77% carbon, 11.63% hydrogen and rest o...

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  8. Explain Nucleophilic addition reaction mechanism of aldehydes and keto...

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  9. Write any two methods for the preparation of Aldehydes.

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  10. Write any two methods for the preparation of Ketones.

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  11. Explain Clemenson's reduction and Wolf Kishmer reduction reactions.

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  12. What is haloform reaction ? Give equation .

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  13. What is Cannizaro reaction ? Give equation .

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  14. What is HVZ reaction ? Give equation.

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  15. Write any three methods for the preparation of Carboxylic acid.

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  16. Explain Ring substitution reactions of aromatic carboxylic acids.

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  17. How do you prepare the Acetyl chloride compound from acetic acid ?

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  18. How do you prepare the Acetamide compound from acetic acid ?

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  19. How do you prepare the Acetic anhydride compound from acetic acid ?

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  20. How do you prepare the Ethyl alcohol compound from acetic acid ?

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