Home
Class 12
PHYSICS
The magnetic moment vectors vecmus and v...

The magnetic moment vectors `vecmu_s` and `vecmu_l` associated with the intrinsic spin angular momentum `vecS` and orbital angular momentum `vecl` respectively, of an electron are predicted by quantum theory (and verified experimentally to a high accuracy to be given by
`vecmu_s=-(e/m)vecS` and `vecmu_l=-((e)/(2m))vecl`
Which of these relations is in accordance with the result expected classically? Outline the derivation of the classical result.

Text Solution

Verified by Experts

Out of the two relations given only one is in accordance with classical physics. This is `vec(mu)_(1) = -((e)/(2m))vec(l)`
It follows from the definitions of `mu_(1)` and l.
`mu = iA = ((-e)/(T)) pi r^(2)`.
`l = m v r = m((2pir)/(T))r`
Where r is the radius of the circular orbi which the electron of mass m and charge (-e) completes in time T.
Divide (i) by (ii) `(mu_(1))/(l) = (-e)/(T) pi r^(2) xx (T)/(m^(2) pi r^(2)) = (-e)/(2m)`
`vec(mu)_(1) = ((-e)/(2m))vec(l)`
Clearly `vec(mu)_(1)` and `vec(l)` will be antiparallel (both being normal to the plane of the orbit)
In contrast `(mu_(s))/(s) = (e)/(m)`. It is obtained on the basis of quantum mechanics.
Promotional Banner

Topper's Solved these Questions

  • MAGNETISM AND MATTER

    VIKRAM PUBLICATION ( ANDHRA PUBLICATION)|Exercise Textual Exercises|27 Videos
  • ELECTROSTATIC POTENTIAL AND CAPACITANCE

    VIKRAM PUBLICATION ( ANDHRA PUBLICATION)|Exercise SAQs|4 Videos
  • MOVING CHARGES AND MAGNETISHM

    VIKRAM PUBLICATION ( ANDHRA PUBLICATION)|Exercise ADDITIONAL EXERCISES|26 Videos

Similar Questions

Explore conceptually related problems

The magnetic moment vectors mu_(s) and mu_(l) associated with the intrinsie spin angular momentum S and orbital angular momentum l, respectively, of an electron are predicted by quantum theory (and verified expenmentally to a high accuracy) to be given by: mu_(s)=-(e//m) S, mu_(1)=-(e//2m)l Which of these relations is in accordance with the result expected classically? Outline the derivation of the classical result.

Spin angular momentum of an electron has no analog in classical mechanics. However, it turns out that the treatment of spin angular momentum is closely analogous to the treatment of orbital angular momentum. Spin angular momentum = sqrt(s(s+1)h) Orbital angular momentum = sqrt(l(l+1)h) Total spin of an atom or ion is a multiple of (1)/(2) . Spin multiplicity is a factor to confirm the electronic configuration of an atom or ion. Spin multiplicity (2 sum s +1) The orbital angular momentum for a 2p-electron is :

Spin angular momentum of an electron has no analog in classical mechanics. However, it turns out that the treatment of spin angular momentum is closely analogous to the treatment of orbital angular momentum. Spin angular momentum = sqrt(s(s+1)h) Orbital angular momentum = sqrt(l(l+1)h) Total spin of an atom or ion is a multiple of (1)/(2) . Spin multiplicity is a factor to confirm the electronic configuration of an atom or ion. Spin multiplicity (2 sum s +1) In any subshell, the maximum number of electrons having same value of spin quantum number is :

Spin angular momentum of an electron has no analog in classical mechanics. However, it turns out that the treatment of spin angular momentum is closely analogous to the treatment of orbital angular momentum. Spin angular momentum = sqrt(s(s+1)h) Orbital angular momentum = sqrt(l(l+1)h) Total spin of an atom or ion is a multiple of (1)/(2) . Spin multiplicity is a factor to confirm the electronic configuration of an atom or ion. Spin multiplicity (2 sum s +1) Total spin of Mn^(2+) = (Z = 25) ion will be :

Just as Bohr.s model of atom was developed on the basis of planck.s quantum theory, wave mechanical model of atom has been developed on the basis of quantum mechanics. The herat of quantum mechanism is Schrodinger wave equation which in turn is based on Heisenberg.s uncetainity principle and de broglie concept of dual nature of matter and radiation. Bohr model could explain the main lines of hydrogen or hydrogenic spectra but could not explain their fine structure. To explain this, it was suggested that each level consists of a number of sublevels, it was suggested that each level consists of a number of sublevels, the transitions between which gave rise to closely spaced lines. The numbers representing the main energy level are called Princiapl Quantum Number (n) while those representing sublevels are called Azimuthal Quantum numbers (l) and these determine the angular momentum of the electron. The orbital angular Number (m) which is just like a further split of a sublevel into finer sublevels. Lastly the electron may rotate or spin about its own axis given rise to Spin Quantum number (s) which determines the angular momentum of the electron. The de Broglie wavelength (lambda) of the electron subjected to an accelerating potential of V volts is given by

Just as Bohr.s model of atom was developed on the basis of planck.s quantum theory, wave mechanical model of atom has been developed on the basis of quantum mechanics. The herat of quantum mechanism is Schrodinger wave equation which in turn is based on Heisenberg.s uncetainity principle and de broglie concept of dual nature of matter and radiation. Bohr model could explain the main lines of hydrogen or hydrogenic spectra but could not explain their fine structure. To explain this, it was suggested that each level consists of a number of sublevels, it was suggested that each level consists of a number of sublevels, the transitions between which gave rise to closely spaced lines. The numbers representing the main energy level are called Princiapl Quantum Number (n) while those representing sublevels are called Azimuthal Quantum numbers (l) and these determine the angular momentum of the electron. The orbital angular Number (m) which is just like a further split of a sublevel into finer sublevels. Lastly the electron may rotate or spin about its own axis given rise to Spin Quantum number (s) which determines the angular momentum of the electron. The quantum number not obtained from the solution of Schrodinger wave equation is

It is tempting to think that all possible transitions are permissible, and that an atomic spectrum arises from the transition of the electron from any initial orbital to any other orbital. However, this is not so, because a photon has an intrinsic spin angular momentum of sqrt2 (h)/(2pi) corresponding to S = 1 although it has no charge and no rest mass. On the other hand, an electron has got two types of angular momentum : Orbital angular momentum, L=sqrt(l(l+1))h/(2pi) and spin angular momentum, arising from orbital motion and spin motion of electron respectively. The change in angular momentum of the electron during any electronic transition mush compensate for the angular momentum carries away by the photon. to satisfy this condition the difference between the azimuthal quantum numbers of the orbital within which transition takes place must differ by one. Thus, an electron in a d-orbital (1 = 2) cannot make a transition into an s = orbital (I = 0) because the photon cannot carry away enough angular momentum. An electron as is well known, possess four quantum numbers n, I, m and s. Out of these four I determines the magnitude of orbital angular momentum (mentioned above) while (2n m determines its z-components as m((h)/(2pi)) the permissible values of only integers right from -1 to + l. While those for I are also integers starting from 0 to (n − 1). The values of I denotes the sub shell. For I = 0, 1, 2, 3, 4,..... the sub-shells are denoted by the symbols s, p, d, f, g, .... respectively The spin-only magnetic moment of free ion is sqrt(8) B.M. The spin angular momentum of electron will be

It is tempting to think that all possible transitions are permissible, and that an atomic spectrum arises from the transition of the electron from any initial orbital to any other orbital. However, this is not so, because a photon has an intrinsic spin angular momentum of sqrt2 (h)/(2pi) corresponding to S = 1 although it has no charge and no rest mass. On the other hand, an electron has got two types of angular momentum : Orbital angular momentum, L=sqrt(l(l+1))h/(2pi) and spin angular momentum, arising from orbital motion and spin motion of electron respectively. The change in angular momentum of the electron during any electronic transition must compensate for the angular momentum carries away by the photon. to satisfy this condition the difference between the azimuthal quantum numbers of the orbital within which transition takes place must differ by one. Thus, an electron in a d-orbital (1 = 2) cannot make a transition into an s = orbital (I = 0) because the photon cannot carry away enough angular momentum. An electron as is well known, possess four quantum numbers n, I, m and s. Out of these four I determines the magnitude of orbital angular momentum (mentioned above) while (2n m determines its z-components as m((h)/(2pi)) the permissible values of only integers right from -1 to + l. While those for I are also integers starting from 0 to (n − 1). The values of I denotes the sub shell. For I = 0, 1, 2, 3, 4,..... the sub-shells are denoted by the symbols s, p, d, f, g, .... respectively The orbital angular momentum of an electron in p-orbital makes an angle of 45^@ from Z-axis. Hence Z-component of orbital angular momentum of election is :

It is tempting to think that all possible transitions are permissible, and that an atomic spectrum arises from the transition of the electron from any initial orbital to any other orbital. However, this is not so, because a photon has an intrinsic spin angular momentum of sqrt2 (h)/(2pi) corresponding to S = 1 although it has no charge and no rest mass. On the other hand, an electron has got two types of angular momentum : Orbital angular momentum, L=sqrt(l(l+1))h/(2pi) and spin angular momentum, arising from orbital motion and spin motion of electron respectively. The change in angular momentum of the electron during any electronic transition must compensate for the angular momentum carries away by the photon. to satisfy this condition the difference between the azimuthal quantum numbers of the orbital within which transition takes place must differ by one. Thus, an electron in a d-orbital (1 = 2) cannot make a transition into an s = orbital (I = 0) because the photon cannot carry away enough angular momentum. An electron as is well known, possess four quantum numbers n, I, m and s. Out of these four I determines the magnitude of orbital angular momentum (mentioned above) while (2n m determines its z-components as m((h)/(2pi)) he permissible values of only integers right from -1 to + l. While those for I are also integers starting from 0 to (n − 1). The values of I denotes the sub shell. For I = 0, 1, 2, 3, 4,..... the sub-shells are denoted by the symbols s, p, d, f, g, .... respectively The maximum orbital angular momentum of an electron with n= 5 is

An orbital is designated by certain values of first three quantum numbers (n, l and m) and according to Pauli.s exclusion principle, no two electrons in a atom can have all the for quantum numbers equal. N, l and m denote size, shape and orientation of the orbital. The permissible values of n are 1,2,3.... prop while that of 1 are all possible integral values from 0 to n-n. Orbitals with same values of n and 1 but different values of m (where m can have any integral values from 1 to +1 including zero) are of equal energy and are called degenerate orbitals. However degeneracy is destroyed in homogeneous external magnetic field due to different extent of interaction between the applied field and internal electronic magnet of different orbitals differing in orientations. In octahedral magnetic field external magnetic field as oriented along axes while in tetrahedral field the applied field actas more in between the axes than that on the axes themselves. For 1=0, 1,2,3,...., the states (called sub-shells) are denoted by the symbol s,p,d,f.....respectively. After f, the subshells are denoted by letters alphabetically 1 determines orbital angular motion (L) of electron as L = sqrt(l(l+1))(h)/(2pi) ON the other hand, m determines Z-component of orbital angular momentum as L_(Z) = m((h)/(2pi)) Hund.s rule states that in degenerate orbitals electrons do not pair up unless and until each each orbitals has got an electron with parallesl spins Besides orbital motion,an electron also posses spin-motion. Spin may be clockwise and anticloskwise. Both these spin motions are called two spins states of electrons characterized by spin Q.N (s) : s = +(1)/(2) and = -(1)/(2) respectively The sum of spin Q.N. of all the electrons is called total spin(s) and 2s+1 is called spin multiplicity of the configuration as a whole. The spin angular momentum of an electron is written as L_(s) = sqrt(s(s+1))(h)/(2pi) The orbital angular momentum of electron (l=1) makes an angles of 45^(@) from Z-axis. The L_(z) of electron will be

VIKRAM PUBLICATION ( ANDHRA PUBLICATION)-MAGNETISM AND MATTER-Additional Exercises
  1. Why does a paramagnetic sample display greater magnetisation (for the ...

    Text Solution

    |

  2. Why is diamagnetism, in contrast, almost independent of temperature?

    Text Solution

    |

  3. If toroid uses bismuth for its core, will the field in the core be (sl...

    Text Solution

    |

  4. Is the permeability of a ferromagnetic material independent of the mag...

    Text Solution

    |

  5. Magnetic field mass lines are always nearly normal to the surface of a...

    Text Solution

    |

  6. Would the maximum possible magnetisation of a paramagnetic sample be o...

    Text Solution

    |

  7. Explain qualitatively on the basis of domain picture the irreversibili...

    Text Solution

    |

  8. The hysteresis loop of a soft iron piece has a much smaller area than ...

    Text Solution

    |

  9. A system displaying a hysterisis loop such as a ferromagnet, is a devi...

    Text Solution

    |

  10. What king of ferromagnetic material is used for coating magnetic tapes...

    Text Solution

    |

  11. A certain region of space is to be shielded from magnetic fields. Sugg...

    Text Solution

    |

  12. A long straight horizontal cable carries a current of 2.5 A in the dir...

    Text Solution

    |

  13. A telephone cable at a place has four long straight horizontal wires c...

    Text Solution

    |

  14. A compass needle free to turn in a horizontal plane is placed at the c...

    Text Solution

    |

  15. A magnetic dipole is under the influence of two magnetic fields. The a...

    Text Solution

    |

  16. A monoenergetic (18 keV) electron beam initially in the horizontal dir...

    Text Solution

    |

  17. A sample of paramagnetic salt contains 2.0 xx 10^(24) atomic dipoles e...

    Text Solution

    |

  18. A Rowland ring of mean radius 15 cm has 3500 turns of wire wound on a ...

    Text Solution

    |

  19. The magnetic moment vectors vecmus and vecmul associated with the intr...

    Text Solution

    |