Home
Class 11
CHEMISTRY
Find the electronegativity of lead with ...

Find the electronegativity of lead with the help of the given valus. Screening consitant `(sigma)` of `Pb = 76.70`. Atomic number of lead `= 82` and covalent radius of `Pb = 5.3 Å`

Text Solution

Verified by Experts

Substituting the value of `sigma`, `Z` and `r` in Allered-Rochow's scale …(i)
`Z_("eff") = Z - sigma = 82-76.70 = 5.3`
`chi_(Pb) = 0.359 xx (Z_("eff"))/(r^(2)) + 0.744`
`= 0.359 xx (5.3)/((5.3)^(2)) + 0.744`
`= 1.55`
Promotional Banner

Topper's Solved these Questions

  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY|Exercise Ex 1.1|14 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY|Exercise Ex 1.1 (Very Short)|22 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY|Exercise Exercises (Archives )Subjective|4 Videos
  • P-BLOCK GROUP 14 - CARBON FAMILY

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Subjective)|9 Videos
  • PURIFICATION OF ORGANIC COMPOUNDS AND QUALITATIVE AND QUANTITATIVE ANALYSIS

    CENGAGE CHEMISTRY|Exercise Assertion Reasoning Type|5 Videos

Similar Questions

Explore conceptually related problems

A sphere of lead of mass 10 g has net charge -25 xx 10^(-9)C . (i) Find the number of excess electrons on the sphere. (ii) How many excess electrons are per lead atom ? Atomic number of lead is 82 and its atomic mass is 207 g/mol.

Mulliken defined the electronegativity of an atom as the arithmetic mean of its ionisation energy and electron affinity. X_(A)=(1)/(2)(I.P.+E.A.) One more relationship given by him, if the values are given in eV is X_(A)=("Ionisation potential"+ "Electron affinity")/(5.6) When there is pure covalent bond between A-B ((IP)_(A)+(EA)_(A))/(5.6)=((IP)_(B)+(EA)_(B))/(5.6) implies X_(A)=X_(B) Pauling's Electronegativity scale is based on

Mulliken defined the electronegativity of an atom as the arithmetic mean of its ionisation energy and electron affinity. X_(A)=(1)/(2)(I.P.+E.A.) One more relationship given by him, if the values are given in eV is X_(A)=("Ionisation potential"+ "Electron affinity")/(5.6) When there is pure covalent bond between A-B ((IP)_(A)+(EA)_(A))/(5.6)=((IP)_(B)+(EA)_(B))/(5.6) implies X_(A)=X_(B) According to Mulliken, electronegativity depends on

J.C. Slater proposed an empirical constant that represents the cumulative extent to which the other electrons of an atom shield (or screen) any particular electron from the nuclear charge. Thus, slater's screening contant sigma is as : Z^(**)=Z-sigma Here, Z is the atomic number of the atom, and hence is equal to the actual number of protons in the atom. the parameter Z^(**) is the effective nuclear charge, which according to is smaller than Z, since the electron in question is screened (shielded) from Z by an amount sigma . Conversely, an electron that is well shielded from the nuclear charge Z experiences a small effective nuclear charge Z^(**) . The value of sigma for any one electron in a given electron configuration (i.e., in the presence of the other electrons of the atom in question) is calculated using a set of empirical rules developed by slater. according to these rules, the value of sigma for the electron in question is the cumulative total provided by the various other electrons of the atom. Q. Which of the following statement is correct?

The radus of hydrogen atom in the ground state 0.53 Å . The radius of Li^(2+) ion (Atomic number = 3) in a similar state is

Medical experts generally consider a lead of 30 mu g Pb per (dL) of blood to pose a significant health risk (Pb = 208) . Number of lead atoms per cm^3 of blood is.

CENGAGE CHEMISTRY-PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY-Solved Examples
  1. For the reaction K(g)+F(g) +K^(o+)+F^(Theta) (separated ions DeltaH = ...

    Text Solution

    |

  2. From N atoms of an element A, when half the atoms transfer one electro...

    Text Solution

    |

  3. The conservation of gaseous atoms K and F to K^(o+) and F^(ɵ) absorbs ...

    Text Solution

    |

  4. Explain the following: a. Which of the following Na, Mg, Si and P wo...

    Text Solution

    |

  5. Classify the following oxides as a. Strongly acidic b. Weakly acidic...

    Text Solution

    |

  6. Select the strongest and weakest acid in each of the following sets: ...

    Text Solution

    |

  7. A 0.10 M aqueous solution of which salt in each of the following pairs...

    Text Solution

    |

  8. Identify: a. The good oxidising agent (s) b. The good reducing age...

    Text Solution

    |

  9. Answer the following: a. Which of the following has the greatest aff...

    Text Solution

    |

  10. Explain the following: a. The formation of Cs(2)O from its element i...

    Text Solution

    |

  11. Give the name and atomic number of the inert gas atom in which the tot...

    Text Solution

    |

  12. Classify the elements having atomic numbers (9,12,16,34,53,56) into th...

    Text Solution

    |

  13. Calculate the electronegativity of fluorine from the following data: ...

    Text Solution

    |

  14. Calculate electronegativity of carbon at Pauling scale Given that : ...

    Text Solution

    |

  15. Ionisation potential and electron affinity of fluorine are 17.42 and 3...

    Text Solution

    |

  16. Calculate the electonegativity of silicon using Allred -Rochow method ...

    Text Solution

    |

  17. Calculate the electronegativity value of chlorine on Mulliken's scale,...

    Text Solution

    |

  18. Find the electronegativity of lead with the help of the given valus. S...

    Text Solution

    |

  19. The ionisation potentials of atoms A and B are 400 and 300 kcal mol^(-...

    Text Solution

    |

  20. Give the names of seven f-orbitals and how they are represented.

    Text Solution

    |