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Which of the following are correct?...

Which of the following are correct?

A

`As^(5+)` salts are better oxidising agents

B

`Tl^(3+)` salts are better oxidising agents

C

`Ga^(o+)` salts are better oxidising agents

D

`Pb^(4+)` salts are better oxidising agents

Text Solution

Verified by Experts

The correct Answer is:
B, C, D

a. `As^(5+)` is stable, but `Sb^(3+)` `Bi^(3+)` are more stable than `+5 OS`.
b. Due to inert pair effect, `Ti^(o+)` (reduction acts as oxidising agent)
Hence, `Ti^(3+)` acts as oxidising agent.
c. For the same reason `Ga^(3+)` is more stable than `Ga^(o+)`.
d. `Pb^(2+)` is more stable than `Pb^(4+)`, due to inert pair effect. So, `Pb^(4+)` salts are better oxidising agents.
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