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The energy required to remove an electro...

The energy required to remove an electron from the outermost shell of an isolate gaseous atom is known as `IE_(1)` of that atom. Similarly, the enrgy required for the removal of the electron from the unipositive ion, diapositive ion and tripositive ion are known as `IE_(2),IE_(3)` and `IE_(4)` respectively, and are called successive ionisation energies. The magnitude of the charge depends on the size of the orbital of electron. Electrons in smaller orbitals are on average close with each other and have more repulsion. Thus for `Be(2s^(2))`, the `IE_(1)` and `IE_(2)` are `9.3` and `18.2 eV "atom"^(1)`, whereas for `Ca(4s^(2))`, the values are `6.1` and `11.9 eV`.
Which of the following are isoelectronic species?
`1 rarrCH_(3)^(o+),IIrarrNH_(2)^(ɵ),IIIrarrNH_(4)^(o+),IVrarrNH_(3)`

A

`I, II` and `III`

B

`II, III`and `IV`

C

`I,II` and `IV`

D

`II` and` I`

Text Solution

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The correct Answer is:
B

`II, III` and `IV` are isoelectronic species.
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The energy required to remove an electron from the outermost shell of an isolate gaseous atom is known as IE_(1) of that atom. Similarly, the enrgy required for the removal of the electron from the unipositive ion, diapositive ion and tripositive ion are known as IE_(2),IE_(3) and IE_(4) respectively, and are called successive ionisation energies. The magnitude of the charge depends on the size of the orbital of electron. Electrons in smaller orbitals are on average close with each other and have more repulsion. Thus for Be(2s^(2)) , the IE_(1) and IE_(2) are 9.3 and 18.2 eV "atom"^(1) , whereas for Ca(4s^(2)) , the values are 6.1 and 11.9 eV . The relationship between IE_(4) and IE_(2) of an element is

The energy required to remove an electron from the outermost shell of an isolate gaseous atom is known as IE_(1) of that atom. Similarly, the enrgy required for the removal of the electron from the unipositive ion, diapositive ion and tripositive ion are known as IE_(2),IE_(3) and IE_(4) respectively, and are called successive ionisation energies. The magnitude of the charge depends on the size of the orbital of electron. Electrons in smaller orbitals are on average close with each other and have more repulsion. Thus for Be(2s^(2)) , the IE_(1) and IE_(2) are 9.3 and 18.2 eV "atom"^(1) , whereas for Ca(4s^(2)) , the values are 6.1 and 11.9 eV . Among the following ionisation reactions, which one will have the maximum value of ionisation energy?

The energy required to remove an electron from the outermost shell of an isolate gaseous atom is known as IE_(1) of that atom. Similarly, the enrgy required for the removal of the electron from the unipositive ion, diapositive ion and tripositive ion are known as IE_(2),IE_(3) and IE_(4) respectively, and are called successive ionisation energies. The magnitude of the charge depends on the size of the orbital of electron. Electrons in smaller orbitals are on average close with each other and have more repulsion. Thus for Be(2s^(2)) , the IE_(1) and IE_(2) are 9.3 and 18.2 eV "atom"^(1) , whereas for Ca(4s^(2)) , the values are 6.1 and 11.9 eV . Consider the IE_(1) of the element whose electronic configuration correspond to the following:

The energy required to remove an electron from the outermost shell of an isolate gaseous atom is known as IE_(1) of that atom. Similarly, the enrgy required for the removal of the electron from the unipositive ion, diapositive ion and tripositive ion are known as IE_(2),IE_(3) and IE_(4) respectively, and are called successive ionisation energies. The magnitude of the charge depends on the size of the orbital of electron. Electrons in smaller orbitals are on average close with each other and have more repulsion. Thus for Be(2s^(2)) , the IE_(1) and IE_(2) are 9.3 and 18.2 eV "atom"^(1) , whereas for Ca(4s^(2)) , the values are 6.1 and 11.9 eV . The correct order of arrangement of the first ionisation energies of C, N,O and F ( in decreasing values) is

The energy required to remove an electron from the outermost shell of an isolate gaseous atom is known as IE_(1) of that atom. Similarly, the enrgy required for the removal of the electron from the unipositive ion, diapositive ion and tripositive ion are known as IE_(2),IE_(3) and IE_(4) respectively, and are called successive ionisation energies. The magnitude of the charge depends on the size of the orbital of electron. Electrons in smaller orbitals are on average close with each other and have more repulsion. Thus for Be(2s^(2)) , the IE_(1) and IE_(2) are 9.3 and 18.2 eV "atom"^(1) , whereas for Ca(4s^(2)) , the values are 6.1 and 11.9 eV . Four elemensts have the following first ionization energies in KJmol^(-1): 762, 709, 59 and 558 . The elements are Ca, Ge . In and Sn (not in order). Which of these elements has the ionisation energy of 762 KJ mol^(-1) ?

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