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The size of isoelectronic species F^(ɵ),...

The size of isoelectronic species `F^(ɵ)`, `Ne`, and `Na^(o+)` is affected by

A

Nuclear charge `(Z)`

B

Valence principal quantum number `(n)`

C

Electron-electron interaction in the outer orbitals

D

None of the factors because their size the same

Text Solution

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The correct Answer is:
To determine the factors affecting the size of isoelectronic species \( F^{-} \), \( Ne \), and \( Na^{+} \), we need to analyze their electronic configurations and the nuclear charge associated with each species. ### Step-by-Step Solution: 1. **Identify the Isoelectronic Species**: - Isoelectronic species are atoms or ions that have the same number of electrons. - In this case, \( F^{-} \), \( Ne \), and \( Na^{+} \) all have 10 electrons. 2. **Determine the Number of Protons**: - **Fluorine (\( F \))**: Atomic number = 9, thus \( F^{-} \) has 9 protons. - **Neon (\( Ne \))**: Atomic number = 10, thus \( Ne \) has 10 protons. - **Sodium (\( Na \))**: Atomic number = 11, thus \( Na^{+} \) has 11 protons (after losing one electron). 3. **Analyze Nuclear Charge**: - The nuclear charge is the total charge of the nucleus due to protons. - The more protons present in the nucleus, the greater the nuclear charge, which affects the attraction between the nucleus and the electrons. 4. **Compare the Nuclear Charges**: - For \( F^{-} \): 9 protons, 10 electrons → Nuclear charge = +9 - For \( Ne \): 10 protons, 10 electrons → Nuclear charge = +10 - For \( Na^{+} \): 11 protons, 10 electrons → Nuclear charge = +11 5. **Determine the Size Based on Nuclear Charge**: - As the nuclear charge increases, the size of the species decreases due to a stronger attraction between the nucleus and the electrons. - Therefore, the order of size will be: - \( F^{-} \) (largest, due to the lowest nuclear charge) - \( Ne \) (intermediate size) - \( Na^{+} \) (smallest, due to the highest nuclear charge) 6. **Conclusion**: - The size of the isoelectronic species is primarily affected by the **nuclear charge**. The greater the nuclear charge, the smaller the size of the ion or atom. ### Final Order of Sizes: - \( F^{-} > Ne > Na^{+} \)
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