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Select from the following molecular orbi...

Select from the following molecular orbitals which are gerade ungerade
(a) `sigma(2s)` (b) `pi^(**)(2p_(x))` (c ) `pi ^(**)(2p_(y))`
(d) `sigma^(**)(1s)` (e) `pi (2p_(x))` (f) `pi (2p_(x))` .

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To determine which of the given molecular orbitals are gerade (G) and ungerade (U), we need to understand the definitions of these terms in the context of molecular orbital theory. **Step 1: Understand the Definitions** - **Gerade (G)**: These are molecular orbitals that remain unchanged in sign when the molecule is inverted through the center of symmetry. In simpler terms, if you rotate the orbital around its center, the phase (sign) of the wave function does not change. - **Ungerade (U)**: These are molecular orbitals that change sign when the molecule is inverted through the center of symmetry. This means that the phase (sign) of the wave function does change upon rotation. **Step 2: Analyze Each Molecular Orbital** Now, we will analyze the given molecular orbitals one by one: ...
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sigma2s, pi^(**) (2p_(x)) and pi(2p_(x)) are gerade MO .

How many nodal planes are present in the following MO's (Taking Z-axis as the internuclear axis) (i) sigma ls (ii) sigma^(**) ls (iii) sigma2p_(z) (iv) sigma^(**)2p_(z) (v) pi 2p_(y) (vi) pi^(**)2p_(x) or pi^(**)2p_(y) Give the number of electrons which occupy the bonding orbitals in H_(2)^(o+) H_(2) and O_(2)^(o+) (c ) Why N_(2) has greater bond dissociation energey than N_(2)^(o+) whereas O_(2)^(o+) has greater bond dissociation energy than O_(2) .

Comprehension given below is followed by some multiple choice question, Each question has one correct options. Choose the correct option. Molecular orbitals are formed by the overlap of atomic orbitals. Two atomic orbitals combine to form two molecular orbitals called bonding molecular orbital (BMO) and anti-bonding molecular orbital (ABMO). Energy of anti-bonding orbital is raised above the parent atomic orbitals that have combined and hte energy of the bonding orbital is lowered than the parent atomic orbitals. energies of various molecular orbitals for elements hydrogen to nitrogen increase in the order sigma1s lt sigma^(star)1s lt sigma^(star)2s lt ((pi2p_(x))=(pi2p_(y))) lt sigma2p_(z) lt (pi^(star)2p_(x) = pi^(star)2p_(y)) lt sigma^(star)2p_(z) and For oxygen and fluorine order of enregy of molecules orbitals is given below. sigma1s lt sigma^(star)1s lt sigma2s lt sigma^(star)2s lt sigmap_(z) lt (pi2p_(x) ~~ pi2p_(y)) lt (pi^(star)2p_(x)~~ pi^(star)2py) lt sigma^(star)2p_(z) Different atomic orbitalsof one atom combine with those atoms orbitals of the second atom which have comparable energies and proper orientation. Further, if the overlapping is head on, the molecular orbital is called sigma, sigma andif the overlap is lateral, the molecular orbital is called pi, pi . The molecular orbitals are filled with electrons according to the same rules as followed for filling of atomic orbitals. However, the order for filling is not the same for all molecules or their ions. Bond order is one of the most important parameters to compare the strength of bonds. 67) Which of the following pair is expected to have the same bonod order?

Comprehension given below is followed by some multiple choice question, Each question has one correct options. Choose the correct option. Molecular orbitals are formed by the overlap of atomic orbitals. Two atomic orbitals combine to form two molecular orbitals called bonding molecular orbital (BMO) and anti-bonding molecular orbital (ABMO). Energy of anti-bonding orbital is raised above the parent atomic orbitals that have combined and hte energy of the bonding orbital is lowered than the parent atomic orbitals. energies of various molecular orbitals for elements hydrogen to nitrogen increase in the order sigma1s lt sigma^(star)1sltsigma^(star)2slt((pi2p_(x))=(pi2p_(y)))ltsigma2p_(z)lt(pi^(star)2p_(x) = pi^(star)2p_(y))ltsigma^(star)2p_(z) and For oxygen and fluorine order of enregy of molecules orbitals is given below. sigma1s lt sigma^(star)1s lt sigma2s lt sigma^(star)2s lt sigmap_(z) lt (pi2p_(x) ~~ pi2p_(y)) lt (pi^(star)2p_(x)~~ pi^(star)2py) lt sigma^(star)2p_(z) Different atomic orbitalsof one atom combine with those atoms orbitals of the second atom which have comparable energies and proper orientation. Further, if the overlapping is head on, the molecular orbital is called sigma, sigma andif the overlap is lateral, the molecular orbital is called pi, pi . The molecular orbitals are filled with electrons according to the same rules as followed for filling of atomic orbitals. However, the order for filling is not the same for all molecules or their ions. Bond order is one of the most important parameters to compare the strength of bonds. 66) Which of the following moleculart orbitals has maximum number of nodal planes?

CENGAGE CHEMISTRY-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Archives Subjective
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