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The molecule having one unpaired electro...

The molecule having one unpaired electrons is .

A

`O_(2)`

B

`CN^(Θ)`

C

`NO`

D

`CO`

Text Solution

Verified by Experts

The electronic cofiguration of each species according to `MO` theory
(a) `O_(2) (8+8 =6e^(-))implies(sigma1s^(2)) (sigma^(**)1s^(2))(sigma2s^(2))(sigma^(**)2s^(2))`
`(sigma 2p_(z)^(2)) (pi 2p_(x)^(2) =pi 2p_(y)^(2))`
`(pi^(**)2p_(x)^(1))(pi^(**)2p_(y)^(1))`
(Two unpaired `e^(-')s`)
(b) `CN^(Θ) (6 +7 + 1 =14e^(-)) implies (sigma 1s^(2)) (sigma^(**)1s^(2)) (sigma2s^(2))`
`(sigma ^(**)2s^(2)) (sigma2p_(z)^(2))` (No unpaired `e^(-')s`)
(c ) `NO (7 +8 = 15e^(-')) implies (sigma 1s^(2)) (sigam ^(**)1s^(2)) (sigma 2s^(2)) (sigma^(**)2s^(2))`
`(sigma 2p_(z)^(2)) (pi2p_(x)^(2)) (pi2p_(y)^(2))(pi^(**)2p_(x)^(1))`
`(sigma 2p_(z)^(2)) (pi2p_(x)^(2))(pi2p_(y)^(2))(pi^(**)2p_(x)^(1))`
(one unapired` e^(-))`
Hence, answer is (c)
(d) `CO (6 +8 = 14 e^(-))` Similar to that of `CN^(Θ)` .
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CENGAGE CHEMISTRY-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Ex 2 .2 Objective
  1. Expalin (a) H(2)^(o+) and H(2)^(Θ) ions have same bond order but H(2...

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  2. Which of the following species have same bond order and same shape (...

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  3. Which of the following is soluble in water

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  4. Which one among the following does not have the hybrogen bond ?

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  5. The molecule having one unpaired electrons is .

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  6. The H-bond is strongest in

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  7. Hydrogen bond is maximum in .

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  8. Number of H-bonds formed by a water molecule is:

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  9. Number of paired electrons in O(2) molecule is .

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  10. Among KO(2),ALO(2)^(Θ) and O(2),unpaired electrons is present in .

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  11. The correct order of decreasing C-O bond length of (1) CO,(II)CO(3)^(2...

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  12. Which of the following statement is correct among the species CN^(Θ),C...

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  13. Which of the following molecular species has unpaired electrons(s) ? .

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  14. Which of the following are isolectronic and iso-structural ? NO(3)^(...

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  15. According to MOT whch of the following statement about magnetic charac...

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  16. Which of the following compound is paramagnetic ? .

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  17. The species having bond order differnet from that in CO is .

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  18. In forming (i) N(2) rarrN(2)^(o+) and O(2)rarrO(2)^(o+) the electrons ...

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  19. Using MOT predict which of the following species has the shortest bond...

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  20. Which of the following has //have identical bond order ?

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