Home
Class 11
CHEMISTRY
Assertion O(2) and N(2)^(2-) have same n...

Assertion `O_(2)` and `N_(2)^(2-)` have same number of electrons and same molecualar orbital configuration
Reasoning `O_(2)` and `N_(2)^(2-)` have the same bond order .

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

B

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

C

If `(A)` is correct but `(R )` is incorrect

D

If `(A)` is incorrect but `(R )` is correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reasoning provided regarding the molecular orbital configurations and bond orders of \(O_2\) and \(N_2^{2-}\). ### Step-by-Step Solution: 1. **Determine the Electron Configuration of \(O_2\)**: - Oxygen (O) has an atomic number of 8, which means each oxygen atom has 8 electrons. Therefore, \(O_2\) has a total of \(8 + 8 = 16\) electrons. - The molecular orbital configuration for \(O_2\) is: \[ \sigma_{1s}^2 \sigma_{1s}^*^2 \sigma_{2s}^2 \sigma_{2s}^*^2 \sigma_{2p_z}^2 \pi_{2p_x}^2 \pi_{2p_y}^2 \pi_{2p_x}^*^1 \pi_{2p_y}^*^1 \] - This results in a bond order of: \[ \text{Bond Order} = \frac{(8 \text{ bonding electrons} - 4 \text{ antibonding electrons})}{2} = \frac{4}{2} = 2 \] 2. **Determine the Electron Configuration of \(N_2^{2-}\)**: - Nitrogen (N) has an atomic number of 7, so each nitrogen atom has 7 electrons. Therefore, \(N_2\) has a total of \(7 + 7 = 14\) electrons. The \(N_2^{2-}\) ion has 2 additional electrons, giving it \(14 + 2 = 16\) electrons. - The molecular orbital configuration for \(N_2^{2-}\) is: \[ \sigma_{1s}^2 \sigma_{1s}^*^2 \sigma_{2s}^2 \sigma_{2s}^*^2 \sigma_{2p_z}^2 \pi_{2p_x}^2 \pi_{2p_y}^2 \pi_{2p_x}^*^1 \pi_{2p_y}^*^1 \] - This also results in a bond order of: \[ \text{Bond Order} = \frac{(8 \text{ bonding electrons} - 4 \text{ antibonding electrons})}{2} = \frac{4}{2} = 2 \] 3. **Compare the Molecular Orbital Configurations**: - Both \(O_2\) and \(N_2^{2-}\) have the same total number of electrons (16) and the same molecular orbital configuration. - However, the assertion that they have the same bond order is incorrect. \(O_2\) has a bond order of 2, while \(N_2^{2-}\) also has a bond order of 2. 4. **Conclusion**: - The assertion is **true**: \(O_2\) and \(N_2^{2-}\) have the same number of electrons and the same molecular orbital configuration. - The reasoning is **false**: While both have the same bond order, the bond order for \(O_2\) is 2, and for \(N_2^{2-}\) is also 2, but the reasoning does not correctly support the assertion. ### Final Answer: - Assertion (A) is correct, and Reasoning (R) is incorrect. Therefore, the answer is **D**.

To solve the question, we need to analyze the assertion and reasoning provided regarding the molecular orbital configurations and bond orders of \(O_2\) and \(N_2^{2-}\). ### Step-by-Step Solution: 1. **Determine the Electron Configuration of \(O_2\)**: - Oxygen (O) has an atomic number of 8, which means each oxygen atom has 8 electrons. Therefore, \(O_2\) has a total of \(8 + 8 = 16\) electrons. - The molecular orbital configuration for \(O_2\) is: \[ ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY|Exercise Exercises Integer|10 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY|Exercise Exercises Fill In The Blanks|20 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY|Exercise Exercises Single Correct (Miscellaneous)|23 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY|Exercise Concept Applicationexercise(4.3)|19 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Archives (Subjective)|11 Videos

Similar Questions

Explore conceptually related problems

Do N_(2)^(+) and O_(2)^(+) have same bond order?

Which two of H_(2)^(+), H_(2)^(-) and H_(2)^(2-) have the same bond order ?

CO_(2) and N_(3)^(Theta) have sane bond order and same shape .

Find the total number of electrons in bonding molecular orbital of O_2^(2-)

Calculate the bond order in (i) H_(2)^(+) (ii) H_(2)^(-) and H_(2)^(2-) have the same bond order?

Are the O.N of oxygen in OF_(2) and Na_(2)O_(2) same or different?

Assertion :- Bond order of O_(2) and BN is same . Reason O_(2) and BN are isoelectronic

N_(2)O and CO_(2) have the same rate of diffusion under same conditions of temperature and pressure. Why ?

CENGAGE CHEMISTRY-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Assetion Reasoning
  1. Assertion NCI(3) reacts with water but NF(3)I s inert towards hydroly...

    Text Solution

    |

  2. Assertion LiF is parctically insoluble in water Reasoning LiF has ve...

    Text Solution

    |

  3. Assertion O(2) and N(2)^(2-) have same number of electrons and same mo...

    Text Solution

    |

  4. Assertion MgCI(2) is more soluble as comared to BeCI(2) Reasoning Be...

    Text Solution

    |

  5. Assertion : H(2) molecule is more stable than He-H molecule . Reaso...

    Text Solution

    |

  6. Assertion Carbon tetrachloride dose not form a percipitate of AgCI wit...

    Text Solution

    |

  7. Assertion Both NO(3)^(Theta) and CO(3)^(2-) ions are triangular planar...

    Text Solution

    |

  8. Assertion H(2)O has maximum density at 4^(@)C Hence in water ice will ...

    Text Solution

    |

  9. Assertion Boiling point of halogen acids are in the order HF gtHBr gt ...

    Text Solution

    |

  10. Assertion Ionic compounds tend to be non-volatile Reasoning Intermol...

    Text Solution

    |

  11. Assertion : Water is a good solvent for ionic compounds but poor one...

    Text Solution

    |

  12. Assertion : The atoms in a covalent molecule are said to share el...

    Text Solution

    |

  13. Assertion (A): Na(2)SO(4) is soluble in water while BaSO(4) is insolub...

    Text Solution

    |

  14. Assertion : The dipole moment helps to predict whether a molecule is ...

    Text Solution

    |

  15. Assertion BF(3) is a weaker Lewis acid than BCI(3) Reasoning In BF(3...

    Text Solution

    |

  16. Bond order for N(2)^(o+) and N(2)^(Theta) are same (i.e2.5) Reasonin...

    Text Solution

    |

  17. Assertion Among two cations of similar size the polarising power of ca...

    Text Solution

    |

  18. Assertion BF(3) has greater dipole momnet than H(2)S Reasoning Fluor...

    Text Solution

    |

  19. Assertion Both pi(2P(x)) and pi^(**)(2P(x))MO's have one nodal plane e...

    Text Solution

    |

  20. Assertion H(2),Li(2),B(2) each has a bond order of 1 and hence are equ...

    Text Solution

    |