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Assertion Boiling point of halogen acids...

Assertion Boiling point of halogen acids are in the order `HF gtHBr gt HCI gt HI`
Reasoning Electronegativities are in the order `F gt CI gt Br gt I` .

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

B

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`

C

If `(A)` is correct but `(R )` is incorrect

D

If `(A)` is incorrect but `(R )` is correct

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The correct Answer is:
D

Boiling point `HF gtHI gt HBr gt HCI HF` has the highest boiling point Consider van der Waals forces of attraction from `HCI` to `HI` Therefore `HF` is liquid and others are gases at room temperature .
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Electronegativity of F gt Cl gt Br gt I , why?

Assertion( A) The boiling points of alkyl halides decrease in the order RI gt RBr gt RCl gt RF Reason (R) The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarbon of comparable molecular mass.

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