Home
Class 11
CHEMISTRY
An aqueous compound of an inorganic comp...

An aqueous compound of an inorganic compound `(X)` shows the following reactions:
a. it decolourises and acidified `KMnO_(4)` solution accompanied by the evolution of oxygen.
b. it liberates `I_(2)` from an acidified `KI` solution.
c. It gives a brown precipitate with alkaline `KMnO_(4)` solution with evolution of oxygen.
d. It removes black stains from old oil paintings. Identify `(X)` and give chemical equtions for the reaction at steps (a) to (d).

Text Solution

Verified by Experts

In reactions (a) and (c), (X) acts as a reducing agent, while in (b), it acts as an oxidising agent. Thus these reactions indicate that `(X)` is `H_(2)O_(2)` which is further confirmed from reactions `(d)`.
a. `underset("coloured")underset("Purple")(2KMnO_(4))+3H_(2)SO_(4)+5H_(2)O_(2)toK_(2)SO_(4)+underset("Colourless")(2MnSO_(4))`
b. `2KI+H_(2)SO_(4)+H_(2)O_(2)toK_(2)SO_(4)+I_(2)+2H_(2)O`
c. `2KMnO_(4)+3H_(2)O_(2)to2KOH+underset("Brown")(2MnO_(2)+2H_(2)O_(2)+3O_(2)`
d. `underset("black")(PbS)+4H_(2)O_(2)tounderset("White")(PbSO_(4))+4H_(2)O`
Promotional Banner

Topper's Solved these Questions

  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY|Exercise Ex 3.1|4 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY|Exercise Ex 3.2|36 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY|Exercise Subjective Archive (Subjective)|3 Videos
  • GENERAL ORGANIC CHEMISTRY

    CENGAGE CHEMISTRY|Exercise Analytical and Descriptive|1 Videos
  • IONIC EQUILIBRIUM

    CENGAGE CHEMISTRY|Exercise Archives Subjective|28 Videos

Similar Questions

Explore conceptually related problems

An aqueous solution of gas ‘A’ gave the following data (reactions): It decolourised an acidified KMnO_(4) solution.

Name the gas that can readily decolourise acidified KMnO_(4) solution: