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Hydrogen peroxide is a powerful oxidisin...

Hydrogen peroxide is a powerful oxidising agent, both in the acidic and alkaline medium.
In acidic medium: `H_(2)O_(2)+2H^(o+)+2e^(ɵ)to2H_(2)O`
In alkaline medium: `H_(2)O_(2)+2e^(ɵ)to2overset(Theta)(O)H`
Hydrogen peroxide acts as a reducing agent towards powerful oxidising agents.
In acidic medium: `H_(2)O_(2)to2H^(o+)+O_(2)+2e^(ɵ)` In alkaline medium, however, its reducing nature is more effective.
`H_(2)O_(2)to2H^(o+)+O_(2)+2e^(ɵ)`
On addition of `H_2O_2` to accidified `KMnO_4, KMnO_4` gets decolourised due to

A

oxidation of `KMnO_(4)`

B

reduction of `KMnO_(4)`

C

both oxidation and reduction

D

none of the above of `KMnO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
B

`{:(2KMnO_(4)+3H_(2)SO_(4)toK_(2)SO_(4)+2MnSO_(4)+2MnSO_(4)+3H_(2)O+5[O]),(5H_(2)O_(2)+5[O]to5H_(2)O+5O_(2)),(ulbar(2KMnO_(4)^(ɵ)+3H_(2)SO_(4)+5H_(2)O_(2)toK_(2)SO_(4)+2MnSO_(4)+8H_(2)O+5O_(2))),(or 2MnO_(4)^(ɵ)+6H^(ɵ)+5H_(2)O_(2)to2Mn^(2+)+8H_(2)O+5O_(2)):}`
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